Publications by authors named "Stephane Marcotte"

This study examined the concentrations of arsenic (As), cadmium (Cd), and mercury (Hg) in rice grains grown in wetlands associated with gold mining in central-southern of Côte d'Ivoire to evaluate potential health risks exposure via rice consumption. In total, 30 rice grains were sampled around Agbaou and Bonikro gold mines. Arsenic and cadmium concentrations were determined using an inductively coupled plasma-optical emission spectrometer (ICP-OES), while atomic absorption spectrometry (AAS) was used for mercury.

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Anthropogenic impacts on rivers have increased significantly over the past ~150 years, particularly at the beginning of the industrial revolution. Among other signs, this impact is manifested through the addition of trace metals and metalloid elements to rivers. The Eure River watershed in France covers an area of 6017 km and is a major tributary of the Seine estuary.

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Pellet stoves arouse a real interest from consumers because they are perceived as a renewable and carbon neutral energy. However, wood combustion can contribute significantly to air pollution, in particular through the emission of particulate matter (PM). In this article, five brands of wood pellets were burnt under optimal combustion conditions and trace element and inorganic salt emission factors (EFs) in PM were determined.

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Lignocellulosic biomass, in particular wood, is a complex mixture containing cellulose, hemicellulose, lignin, and other trace compounds. Chemical analysis of these biomasses, especially lignin components, is a challenge. Lignin is a highly reticulated polymer that is poorly soluble and usually requires chemical, enzymatic, or thermal degradation for its analysis.

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Article Synopsis
  • * The study demonstrated that GC×GC-EI-MS significantly improved peak separation compared to traditional GC-EI-MS, although the Orbitrap mass analyzer had limitations in data acquisition rate, which could affect the resolution of narrow chromatographic peaks.
  • * The analysis of a cellulose bio-oil sample using GC×GC-MS resulted in a well-resolved chromatogram that allowed for the identification of various molecules based on their EI mass spectra, showcasing the technique's effectiveness in bio-oil analysis.
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A cotransport study of heavy metals and kaolinite particles in sand column with and without flax geotextiles was carried out. The objectives were to evaluate the potential role of kaolinite in heavy metals transfer and to analyse the influence of flax geotextiles on the transfer of these pollutants. The adsorption rates of heavy metals on the kaolinite particles were, respectively, 53%, 65% and 25% for copper, lead, and zinc.

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Filtration tests were carried out in laboratory columns filled with crushed sand with and without flax geotextiles to study the transfer and retention of soluble heavy metals. Divalent cations of copper, zinc and lead were simultaneously and continuously injected in filtration columns. Results show that, when geotextiles discs are present the retention of metals in sand is favoured and retention profiles are modified.

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A method was developed for the determination of iodine in polyamide (PA). This method is needed as PA containing iodine (such as CuI/KX (X = I or Br) heat stabilizing agent), may represent a risk of corrosion for electronic parts in the automotive industry. The method involved a microwave assisted digestion method using nitric acid followed by inductively coupled plasma mass spectrometry (ICP-MS) analysis.

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This data article is issued from the research article ''Distribution trends and ecological risks of arsenic and trace metals in wetland sediments around gold mining activities in central-southern and southeastern Côte d'Ivoire'' [1]. It presents arsenic and trace metal Cd, Pb, Cu, Zn, Cr, Co, Fe, Al, Mn, and Ni loadings in surface sediments collected from industrial mining, artisanal and small scale mining, and non-mining areas (West Africa). Are also provided, hierarchical dendrograms and factor loadings derived from the Hierarchical Clustering Analysis (HCA) and the principal component analysis (PCA), respectively.

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Natural geotextiles are increasingly used in geotechnical applications such as bank protection and short-term soil reinforcement. This study aimed to highlight the behaviour of natural flax fibre geotextiles towards the retention of suspended particles (SP) present in urban runoff and often polluted. Indeed, it is well known that a large fraction of the heavy metals are often associated with the SP.

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In recent years, due to their economic and ecological advantages, green infrastructures for stormwater management have been widely implemented. The present study focused on vegetated swales and compared two vegetated covers, grassed or planted with macrophytes in order to evaluate their performance in terms of water quality improvement. These swales collected runoff of a moderately busy road (<2500vehday(-1)) in a commercial area.

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[reaction: see text] The stereocontrolled synthesis of malayamycin A, a novel naturally occurring bicyclic C-nucleoside of the perhydrofuropyran type, is described.

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