Publications by authors named "Stefan Resch"
Article Synopsis
- A flexible macrocyclic ligand can host two different states of copper ions, Cu Cu (1) and mixed-valent Cu Cu (2), which can interconvert reversibly.
- Characterization of these states was done using techniques like X-ray diffraction (XRD) and various spectroscopies, linking their properties to calculations from theoretical methods.
- The electron transfer between these two states occurs quickly despite changes in structure, mirroring mechanisms observed in biological systems that involve flexible copper complexes.
Data on road-killed animals is essential for assessing the impact of roads on biodiversity. In most European countries data on road-killed huntable wildlife exists, but data on other vertebrate species (e.g.
View Article and Find Full Text PDFA neutral hybrid macrocycle with two trans-positioned N-heterocyclic carbenes (NHCs) and two pyridine donors hosts copper in three oxidation states (+I-+III) in a series of structurally characterized complexes (1-3). Redox interconversion of [LCu] is electrochemically (quasi)reversible and occurs at moderate potentials (E =-0.45 V and +0.
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