Strategies to Enhance Carbon Dioxide Capture in Metal-Organic Frameworks.

The dramatic increase of atmospheric CO concentration is responsible for a fast and potentially unpredictable global climate change. Therefore, the implementation of negative carbon technologies such as direct air capture (DAC) is needed. Metal-organic frameworks (MOFs) have the potential to perform CO DAC and achieve unprecedented performances.

Revealing the Initial Reaction Behavior in the Continuous Synthesis of Metal-Organic Frameworks Using Real-Time Synchrotron X-ray Analysis.

In recent years, continuous process technologies have attracted increasing attention, as a means of overcoming limitations in the repeatability and reproducibility of metal-organic framework (MOF) synthesis. Research in this area, however, has neglected to provide insight into the phenomenon leading to the formation of MOFs. In this work, we report the adaption of high-energy synchrotron powder X-ray diffraction analysis to a continuous ZIF-8 production process for online monitoring of the reaction behavior and crystallite formation during the first seconds of the MOF synthesis.