Palladium(II)- and platinum(II)phenyl-2,6-bis(oxazole) pincer complexes: syntheses, crystal structures, and photophysical properties.

Phenyl-2,6-bis(oxazole) ligands have been explored for the synthesis of novel palladium(II) and platinum(II) pincer complexes. The materials were characterized by spectroscopic methods and by X-ray crystallography. Investigations of the photophysical properties revealed that the lowest triplet states of the materials are largely centred at the bis(oxazole) ligands.