Instrumental improvements for the trace analysis of structural isomers of polycyclic aromatic hydrocarbons with molecular mass 302 Da.

Polycyclic aromatic hydrocarbons (PAHs) are some of the most common environmental pollutants encountered worldwide. Eco-toxicological studies attribute a significant portion of the biological activity of PAH contaminated samples to the presence of high molecular weight PAHs (HMW-PAHs), i.e.

Near-field radiative heat transfer between macroscopic planar surfaces.

Near-field radiation allows heat to propagate across a small vacuum gap at rates several orders of magnitude above that of far-field, blackbody radiation. Although heat transfer via near-field effects has been discussed for many years, experimental verification of this theory has been very limited. We have measured the heat transfer between two macroscopic sapphire plates, finding an increase in agreement with expectations from theory.

Phase effects in the diffraction of light: beyond the grating equation.

Diffraction gratings affect the absolute phase of light in a way that is not obvious from the usual derivation of optical paths using the grating equation. For example, consider light which encounters first one and then the second of two parallel gratings. If one grating is moved parallel to its surface, the phase of the light diffracted from the grating pair is shifted by 2pi each time the grating is moved by one grating constant, even though the geometric path length is not altered by the motion.