Metal nanoparticles (NPs) can be employed to modify the emission level of a dye emitter by tailoring the spectral overlap of the optical gain and localized surface plasmon resonance (LSPR). In the case of plasmonic random lasers, tuning the spectral overlap by manipulating metal NPs changes the scattering properties of the system, which is crucial in random lasers (RLs). In order to overcome this drawback, the emitter gain spectrum across the LSPR is tuned by appropriately choosing various dye emitters.
View Article and Find Full Text PDFNitrogen-doped carbon dots (NCDs), exhibiting strong yellow emission in aqueous solution and solid matrices, have been utilized for fabricating heterostructure white electroluminescence devices. These devices consist of nitrogen-doped carbon dots as an emissive layer sandwiched between an organic hole transport layer (PEDOT:PSS) and an array of rutile TiOnanorods, acting as an electron transport layer. Under an applied forward bias of 5 V, the device exhibits broadband electroluminescence covering the wavelength range of 390-900 nm, resulting in pure white light emission characteristics at room temperature.
View Article and Find Full Text PDFPhotocatalytic hydrogen generation from water splitting is regarded as a sustainable technology capable of producing green solar fuels. However, the low charge separation efficiencies and the requirement of lowering redox potentials are unresolved challenges. Herein, a multiphase copper-cuprous oxide/polypyrrole (PPy) heterostructure has been designed to identify the role of multiple oxidation states of metal oxides in water reduction and oxidation.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2022
Transition-metal tellurides (TMTs) are promising materials for "post-graphene age" nanoelectronics and energy storage applications owing to their industry-standard compatibility, high electron mobility, large spin-orbit coupling (SOC), etc. However, tellurium (Te) having a larger ionic radius ( = 52) and broader d-bands endows TMTs with semimetallic nature, restricting their application in photonic and optoelectronic domains. In this work, we report the optical properties of the quantum-confined semiconducting phase of cobalt ditelluride (CoTe) for the first time, exhibiting excellent two-color band photoabsorption attributes covering the UV-visible and near-infrared regions.
View Article and Find Full Text PDFWe have studied the piezo-phototronic induced enhancement in the photo-response of CdS/ZnO heterojunctions attached with plasmonic Au nanoparticle loaded 2D-graphitic carbon nitride (g-C3N4). The hybrid g-C3N4/CdS/ZnO heterojunction favours the charge carrier separation through the formation of a step-like band alignment. Furthermore, the integration of plasmonic Au loaded g-C3N4 nanosheets on the conventional CdS/ZnO heterojunction facilitates improved visible light absorption properties.
View Article and Find Full Text PDF