Nanoconfined Electrochemical Sensing of Single Silver Nanoparticles with a Wireless Nanopore Electrode.

Single entity electrochemistry (SEE) has emerged as a promising method for precise measurement and fundamental understanding of the heterogeneity of single entities. Herein, we propose the dual responsive SEE sensing of the silver nanoparticles (AgNPs) collisions through a wireless nanopore electrode (WNE). Given the high temporal resolution and low background noise features, the Faradaic and capacitive currents provide the AgNPs' collision response.

Joule Heating Effects on Transport-Induced-Charge Phenomena in an Ultrathin Nanopore.

Transport-induced-charge (TIC) phenomena, in which the concentration imbalance between cations and anions occurs when more than two chemical potential gradients coexist within an ultrathin dimension, entail numerous nanofluidic systems. Evidence has indicated that the presence of TIC produces a nonlinear response of electroosmotic flow to the applied voltage, resulting in complex fluid behavior. In this study, we theoretically investigate thermal effects due to Joule heating on TIC phenomena in an ultrathin nanopore by computational fluid dynamics simulation.

Thermodynamic Stability Analysis of Microbubbles Confined in a Liquid Droplet.

A thermodynamic stability analysis of microbubbles in an enclosed volume of a volatile liquid-noncondensable gas solution was performed. The stability conditions for the formation of the bubbles and the relationship between the equilibrium bubble radius and the equilibrium bubble number were investigated. The calculation results show that even if the saturation vapor pressure of a volatile liquid is higher than the pressure of the liquid phase, stable noncondensable gas bubbles appear in a closed system.