Lead zirconate (PbZrO, PZ) is a prototype antiferroelectric (AFE) oxide from which state-of-the-art energy storage materials are derived by chemical substitutions. A thorough understanding of the structure-property relationships of PZ-based materials is essential for both performance improvement and the design of more environmentally friendly replacements. (PbBa)ZrO (PBZ) can serve as a model system for studying the effect of A-site substitution in the perovskite lattice, with barium destabilizing the AFE state.
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