Plasmonic nanoparticle sensors: current progress, challenges, and future prospects.

Plasmonic nanoparticles (NPs) have played a significant role in the evolution of modern nanoscience and nanotechnology in terms of colloidal synthesis, general understanding of nanocrystal growth mechanisms, and their impact in a wide range of applications. They exhibit strong visible colors due to localized surface plasmon resonance (LSPR) that depends on their size, shape, composition, and the surrounding dielectric environment. Under resonant excitation, the LSPR of plasmonic NPs leads to a strong field enhancement near their surfaces and thus enhances various light-matter interactions.

Clustering triggered emissive liquid crystalline template for dual mode upconverted and downconverted circularly polarized luminescence.

Liquid crystalline materials have attracted significant attention in chiroptical research due to their ability to form long range ordered helical superstructures. Research focus has been on exploiting the unique properties of liquid crystalline materials to demonstrate highly dissymmetric circularly polarised luminescent (CPL) systems. In this study, we present a thermally driven, facile approach to fabricate CPL-active materials utilizing cholesteryl benzoate as the active substrate.

Engineering copper plasmonic chirality ligand-induced dissolution for enantioselective recognition of amino acids.

The formation of chiral nanosystems and their subsequent enantioselective interaction with chiral amino acids are vital steps in many biological processes. Due to their potential to mimic biological systems, the synthesis of chiral nanomaterials has garnered significant attention over the years. Despite the emergence of diverse nanomaterials showcasing strong chiral responses, the in-depth understanding of the mechanism of plasmonic chirality in copper nanoparticles and their subsequent application in various fields are least explored.

Dual emissive optically active gold nanoclusters endowed with circularly polarized phosphorescence.

Enantiomerically pure Au nanoclusters exhibiting dual-emission corresponding to fluorescence and phosphorescence were synthesized by adopting a facile approach. Chiral luminescence was observed for the triplet emission leading to circularly polarized phosphorescence, both in solution and in solid states. The nanoclusters exhibited aggregation induced emission, and the aggregated clusters exhibited chiral phosphorescence.

Delayed luminescence guided enhanced circularly polarized emission in atomically precise copper nanoclusters.

Metal nanoclusters, owing to their intriguing optical properties, have captivated research interest over the years. Of special interest have been chiral nanoclusters that display optical activity in the visible region of the electromagnetic spectrum. While the ground state chiral properties of metal nanoclusters have been reasonably well studied, of late research focus has shifted attention to their excited state chiral investigations.

Surfactant Directed Synthesis of Intrinsically Chiral Plasmonic Nanostructures and Precise Tuning of their Optical Activity through Controlled Self-Assembly.

Fabrication and transmission of plasmonic chirality is a rapidly developing area of research. While nanoscale chirality is reasonably well explored, research on intrinsically chiral nanostructures, that has ramifications to origin of homochirality, is still in its infancy. Herein, we report the synthesis of dog-bone shaped chiral gold nanostructures using a chiral cationic surfactant with excess ascorbic acid.

Transmitting biomolecular chirality into carbon nanodots: a facile approach to acquire chiral light emission at the nanoscale.

Since the observation of chirality at the nanoscale, research focused towards the design and synthesis of optically active nanomaterials has been at a brisk pace. In this regard, carbon based zero dimensional nanomaterials have attracted vast attention due to their rich optical properties, abundance of raw materials, minimal environmental hazardousness, good solubility, and ease of surface modification. However, efforts focused towards the synthesis of chiral carbon nanodots exhibiting optical activity both in their ground and excited states are rather scarce.

Mandelic acid appended chiral gels as efficient templates for multicolour circularly polarized luminescence.

Mandelic acid is a medicinally important chiral molecule that is widely used as a vital component in antibiotics, antiseptics and cosmetics. While the medicinal properties of mandelic acid are well known, its aggregation and gelation characteristics, which are crucial to finding applications as cosmetics and ointments, are least explored. We have designed and synthesized a pair of mandelic acid derivatives and investigated their aggregation properties in binary solvent mixtures.

Template Assisted Generation of Chiral Luminescence in Organic Fluorophores.

Development of efficient ways of fabricating chiral light emitting materials is an active area of research due to the vast potential offered by these materials in the field of optoelectronic devices, data storage, and asymmetric synthesis. Among the various methods employed, template assisted generation of chiral luminescence is gaining enormous attention due to its simplicity, applicability over a wide range of fluorescent molecules/dyes, and the display of high anisotropic values.

Plasmon-Enhanced Optical Chirality through Hotspot Formation in Surfactant-Directed Self-Assembly of Gold Nanorods.

Plasmonically enhanced optical dichroism has attracted substantial interest for its application in optical sensing, where the interplay between chirality emanating from both molecules and plasmon-supporting structures has been regarded as a critical ingredient. Here, we experimentally demonstrate that suitably self-assembled achiral plasmonic nanostructures produce a high degree of enhancement in the optical dichroism observed from chiral molecules placed in their vicinity. Specifically, we identify a near-field enhancement associated with plasmonic hotpots as the mechanism enabling our observation of visible-NIR circular dichroism emanating from small amounts of chiral molecules.