J Phys Chem C Nanomater Interfaces
January 2010
The voltammetry of 2,3,5,6-tetramethyl-p-phenylenediamine, HPD, has been studied and compared to that of its isomer N,N,N'N'-tetramethyl-p-phenylenediamine, MePD. Both undergo two reversible electron transfer processes in acetonitrile that nominally correspond to 1e- oxidation to the radical cations, MePD and HPD, and a second 1e- oxidation at more positive potentials to the quinonediimine dications, MePD and HPD. While the voltammetry of MePD agrees with this simple mechanism, that of HPD does not.
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