Engineering Innovations, Challenges, and Opportunities for Lignocellulosic Biorefineries: Leveraging Biobased Polymer Production.

Alternative polymer feedstocks are highly desirable to address environmental, social, and security concerns associated with petrochemical-based materials. Lignocellulosic biomass (LCB) has emerged as one critical feedstock in this regard because it is an abundant and ubiquitous renewable resource. LCB can be deconstructed to generate valuable fuels, chemicals, and small molecules/oligomers that are amenable to modification and polymerization.

Photodegradation of polyolefin thin films in simulated freshwater conditions.

Polypropylene (PP) and polyethylene (PE) are commonly used polyolefins in a variety of applications, which have resulted in their accumulation in the environment. Once in the environment, these polymers undergo various chemical and physical transformations as the result of environmental stressors such as sunlight. While photodegradation has been studied for decades, there are key gaps in knowledge on the phototransformations of polyolefins that occur under aqueous conditions.