Silver Nanoparticle-Incorporated Defect-Engineered Zr-based Metal-Organic Framework for Efficient Multicomponent Catalytic Reactions.

Small-sized silver nanoparticles are incorporated into a thiol-functionalized stable Zr-based metal-organic framework (MOF). Thiol functionalization has been carried out using 2-mercapto benzoic acid (2-MBA) as the modulator, which promotes defect formation in the MOF structure. The incorporation of silver nanoparticles aided by the silver-sulfur interactions in this defective MOF gives rise to catalytic activity.