For the first time, a synergistic energy-efficient combination of microwave-xenon (MW-XE) irradiations in presence of photoactive ternary acidic deep eutectic solvents (TADES) has been applied for intensification of ethyl levulinate synthesis from delignified sugarcane bagasse (DSB) under mild (90 min, 90 °C) and environmentally benign process conditions. The Taguchi orthogonal designed optimized conditions (20 W/cm of MW specific irradiation power input, 1 mol/mol of FeCl to citric acid ratio, 90 min of reaction time, 150 W of XE specific power input) rendered maximum 61.3 mol% of EL yield (selectivity: 87.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
February 2023
An exploratory work involving waste printed wiring board (WPWB)-derived inexpensive silver oxide (AgO)-grafted silica-alumina composite photocatalyst (SAA) using quartz halogen and UVA irradiations (QHUV) (wavelength: 315 nm-1000 nm) has been revealed. The efficacy of the novel SAA photocatalyst was assessed in the synthesis of fermentable sugar (FS) by photo-hydrolysis of pure crystalline cellulose (PCC) in the QHUV-assisted batch reactor (QHUVBR), and the process parameters (5% AgNO doping, 7.5% catalyst concentration, 20 min PH time, and 80 °C PH temperature) were optimized using Taguchi orthogonal array design.
View Article and Find Full Text PDFThis article reports an energy-efficient green pathway for the sustainable conversion of an abundant agro-residue viz. wheat husk (WH) into fermentable sugar (FS). The intensification effects of tungsten-halogen (TH) (150 W) and ultraviolet (UV) (100 W) irradiations on the pretreatment and subsequent hydrolysis of WH have been experimented with and optimized by Taguchi Orthogonal Design Array (TODA).
View Article and Find Full Text PDFLactate plays a crucial role in the anaerobic metabolic pathway of humans. In situations of oxygen deficit, its production increases; leading to several life-threatening conditions such as hemorrhage, respiratory failure, trauma or ischemia from lactate acidosis. Lactate level detection and point-of-care (POC) monitoring in a fast, accurate and non-invasive manner is ultimately important for many health care applications.
View Article and Find Full Text PDFPotential applications of thin film metamaterials are diverse and their realization to offer miniaturized waveguides, antennas and shielding patterns are on anvil. These artificially engineered structures can produce astonishing electromagnetic responses because of their constituents being engineered at much smaller dimensions than the wavelength of the incident electromagnetic wave, hence behaving as artificial materials. Such micro-nano dimensions of thin film metamaterial structures can be customized for various applications due to their exclusive responses to not only electromagnetic, but also to acoustic and thermal waves that surpass the natural materials' properties.
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