Correction: Atmospheric chemistry of ()- and ()-1,2-dichloroethene: kinetics and mechanisms of the reactions with Cl atoms, OH radicals, and O.

Correction for 'Atmospheric chemistry of ()- and ()-1,2-dichloroethene: kinetics and mechanisms of the reactions with Cl atoms, OH radicals, and O' by Mads P. Sulbaek Andersen , , 2022, , 7356-7373, https://doi.org/10.

Atmospheric chemistry of ()- and ()-1,2-dichloroethene: kinetics and mechanisms of the reactions with Cl atoms, OH radicals, and O.

Smog chambers interfaced with FT-IR detection were used to investigate the kinetics and mechanisms of the Cl atom, OH radical, and O initiated oxidation of ()- and ()-1,2-dichloroethene (CHClCHCl) under atmospheric conditions. Relative and absolute rate methods were used to measure (Cl + ()-CHClCHCl) = (8.80 ± 1.

Trichloroacetyl chloride, CClCOCl, as an alternative Cl atom precursor for laboratory use and determination of Cl atom rate coefficients for n-CH[double bond, length as m-dash]CH(CH)CN (x = 3-4).

An investigation of CCl3COCl was conducted with the purpose of using the compound as an alternative Cl atom precursor in laboratory settings. CCl3COCl can be used with or without O2 as a source of Cl atoms and photolysis studies in air and N2 diluent displayed COCl2 and CO as being the major photolysis products. Relative rate studies were performed to determine the Cl atom rate coefficients for reaction with CH3Cl and C2H2 and the results were in agreement with literature values.

Photochemistry of 2,2-dichloroethanol: kinetics and mechanism of the reaction with Cl atoms and OH radicals.

Smog chamber/FTIR techniques were used to investigate the kinetics and mechanism of the Cl atom and OH radical initiated oxidation of 2,2-dichloroethanol at (296 ± 1) K. Relative rate methods were used to measure k(Cl + CHClCHOH) = (5.87 ± 0.

Atmospheric Chemistry of Pentafluorophenol: Kinetics and Mechanism of the Reactions of Cl Atoms and OH Radicals.

Fourier transform infrared smog chamber techniques were used to study the kinetics and mechanisms of the reactions of Cl atoms and OH radicals with pentafluorophenol (CFOH) in 700 Torr total pressure of air or N diluent at 296 ± 2 K. Rate constants (OH + CFOH) = (6.88 ± 1.

Atmospheric Chemistry of n-CH═CH(CH) CN ( x = 0-4): Kinetics and Mechanisms.

Smog chamber/Fourier transform infrared (FTIR) techniques were used to measure the kinetics of the reaction of n-CH═CH(CH) CN ( x = 0-4) with Cl atoms, OH radicals, and O: k(CH═CHCN + Cl) = (1.03 ± 0.13) × 10, k(CH═CHCHCN + Cl) = (2.