Tuning Electron-Transfer Driving Force in Photosynthetic Special Pair Models.

Visible-light excitation of a family of bimetallic ruthenium polypyridines with the formula [Ru(tpy)(bpy)(-CN)Ru(py)L] (RuRuL), where L=Cl, NCS, DMAP and ACN, was used to prepare photoinduced mixed-valence (PI-MV) MLCT states as models of the photosynthetic reaction center. Ultrafast transient absorption spectroscopy allowed to monitor photoinduced IVCT bands between 6000 and 11000 cm. Mulliken spin densities resulting from DFT and (TD)DFT computations revealed the modulation of the charge density distribution depending on the ligand substitution pattern.

Occupational Therapy Practice in the Rehabilitation of Adults with Occupational Dysfunction following a Neurological Injury in Argentina: A Descriptive Study.

To describe aspects of occupational therapy practice in the rehabilitation of adults with occupational dysfunction following a neurological injury in Argentina, a cross-sectional, descriptive study was conducted. One hundred and sixty-seven occupational therapists completed an online, self-administered questionnaire. The preferred professional model was the Model of Human Occupation and the most frequently administered assessment was the Functional Independence Measure.

[Occupational Therapy intervention after a cerebrovascular accident: case report.].

The sequelae produced by a cerebrovascular accident (CVA) have an impact on occupational performance and restrict the person's participation in their occupational roles. C. is a 31-year-old young adult who, after having suffered an ischemic stroke, enters an inpatient rehabilitation center for patients with neurological injury and receives occupational therapy treatment.

Synthesis, UV-visible spectroelectrochemistry and theoretical characterization of new polypyridyl Ru(II) complexes containing 2,4,6-tris(2-pyridyl)-1,3,5-triazine as precursors for water oxidation catalysts.

In this work, we report the syntheses and physicochemical characterization of new chloro and aqua complexes of Ru(ii) with 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz) and 2,2'-bipyridines substituted with donor and acceptor groups in the 4,4'-positions. The aqua complexes behave as precursors for water oxidation catalysts at pH = 1 using Ce(iv) as a sacrificial oxidant. Besides, the oxidized forms Ru(iv) and Ru(v) have been characterized at different pH values by electrochemistry, UV-Visible spectroscopy and spectroelectrochemistry.

Does geometry matter? Effect of the ligand position in bimetallic ruthenium polypyridine siblings.

In this work, we present the preparation of a complex [(tpy)(bpy)Ru(μ-CN)Ru(py)4(OH2)](PF6)3 (tpy = 2,2',6',2''-terpyridine; bpy = 2,2'-bipyridine; py = pyridine) that combines a ruthenium chromophore linked to another ruthenium ion that bears a labile position trans to the bridge. Substitution in this position is very attractive, as it allows us to place a quencher trans to the chromophore maximizing the separation between them. This complex allowed us to prepare a family of cyanide-bridged ruthenium polypyridines of general formula [Ru(tpy)(bpy)(μ-CN)Ru(py)4(L)]2/3+ (L = Cl-, NCS-, 4-dimethylaminopyridine or acetonitrile) and compare them with the related complexes [Ru(tpy)(bpy)(μ-CN)Ru(bpy)2(L)]2/3+ where the L ligand lies cis to the bridge.