Spectrochim Acta A Mol Biomol Spectrosc
November 2008
Palladium(II) and platinum(II) complexes having the general composition [M(L)] X2 (where M=Pd(II) and Pt(II), L=3,4,12,13-tetraphenyl-2,5,11,14,19,20-hexaaza tricyclo [13.3.1.
View Article and Find Full Text PDFA series of metal complexes of Cu(II) and Ni(II) having the general composition [M(L)X(2)] with benzil bis(thiosemicarbazone) has been prepared and characterized by element chemical analysis, molar conductance, magnetic susceptibility measurements, and spectral (electronic, IR, EPR, mass) studies. The IR spectral data suggest the involvement of sulphur and azomethane nitrogen in coordination to the central metal ion. On the basis of spectral studies, an octahedral geometry has been assigned for Ni(II) complexes but a tetragonal geometry for Cu(II) complexes.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2008