Comparison of cadmium pathways in a high Cd accumulating cultivar versus a low Cd accumulating cultivar of Theobroma cacao L.

Understanding cadmium (Cd) pathways in cacao trees is critical for developing Cd mitigation strategies. This study investigates whether Cd uptake and translocation mechanisms differ between a low and a high Cd-accumulating cacao cultivar. We sampled three replicate trees of each cultivar, and a grafted cultivar that shared the same scion as the low Cd accumulator but had a different rootstock.

Acidic hydrothermal processing of wheat using citrate buffer largely enhances iron and zinc bioaccessibility and bioavailability to Caco-2 cells.

Phytate chelates iron (Fe) and zinc (Zn) in wheat. A multifactorial experiment showed that hydrothermal processing (45-60 °C, pH 4.0-6.

Using optimized monochromatic energy dispersive X-ray fluorescence to determine the cadmium concentration in cacao and soil samples.

Following the implementation of food safety limits on cadmium (Cd) in cacao products, there has been a growing demand for monitoring Cd in cacao tissues and soils. Traditional methods like acid digestion followed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) are time-consuming and costly. X-ray Fluorescence is an alternative technique that offers advantages in terms of speed, cost, ease of use and less environmental impact.

Highly weathered mineral soils have highest transfer risk of radiocaesium contamination after a nuclear accident: A global soil-plant study.

Accidental release of radiocaesium (Cs) from nuclear power plants may result in long-term contamination of environmental and food production systems. Assessment of food chain contamination with Cs relies on Cs soil-to-plant transfer data and models mainly available for regions affected by the Chornobyl and Fukushima accidents. Similar data and models are lacking for other regions.

Cadmium concentrations in pore waters can largely increase during soil incubation: Artefacts with consequences for Cd limits in fertilisers.

A sound evaluation of the cadmium (Cd) mass balance in agricultural soils needs accurate data of Cd leaching. Reported Cd concentrations from in situ studies are often one order of magnitude lower than predicted by empirical models, which were calibrated to pore water data from stored soils. It is hypothesized that this discrepancy is related to the preferential flow of water (non-equilibrium) and/or artefacts caused by drying and rewetting soils prior to pore water analysis.

Recycled Iron Phosphates: A New Phosphorus Fertilizer for Paddy Rice.

The potential of recycled iron phosphates (FePs), e.g., vivianites (Fe(PO)·8HO) and Fe(III)-rich phosphorus (P) adsorbent materials, as phosphorus fertilizer is limited by the strong interaction between Fe and P.

Cottage industry as a source of high exposure to lead: A biomonitoring study among people involved in manufacturing cookware from scrap metal.

In low-income countries, a widespread but poorly studied type of cottage industry consists of melting scrap metal for making cookware. We assessed the exposure to lead (Pb) among artisanal workers, and their families, involved in manufacturing cookware from scrap metal. In a cross-sectional survey, we compared artisanal cookware manufacturing foundries with carpentry workshops (negative controls) and car battery repair workshops (positive controls), all located in residential areas, in Lubumbashi (DR Congo).

Do contaminants compromise the use of recycled nutrients in organic agriculture? A review and synthesis of current knowledge on contaminant concentrations, fate in the environment and risk assessment.

Use of nutrients recycled from societal waste streams in agriculture is part of the circular economy, and in line with organic farming principles. Nevertheless, diverse contaminants in waste streams create doubts among organic farmers about potential risks for soil health. Here, we gather the current knowledge on contaminant levels in waste streams and recycled nutrient sources, and discuss associated risks.

Internal loading of phosphorus in streams described by a Sediment-Water Exchange Model for Phosphorus (SWEMP): From lab to field scale.

The reaction of phosphorus (P) between sediments and water in streams strongly affects the surface water P concentrations. A new reactive transport model (SWEMP: Sediment-Water Exchange Model for Phosphorus) was developed to describe redox dependent P sorption in the sediment and vertical diffusive transport of solutes to the overlying stream. The model parameters were independently obtained to first predict P release in ten different sediment-water batch systems and in two flumes.

Extrapolating Metal (Cu, Ni, Zn) Toxicity from Individuals to Populations Across Daphnia Species Using Mechanistic Models: The Roles of Uncertainty Propagation and Combined Physiological Modes of Action.

Mechanistic effect modeling is a promising tool to improve the ecological realism of environmental risk assessment. An open question for the mechanistic modeling of metal toxicity is whether the same physiological mode of action (PMoA) could be assumed for closely related species. The implications of various modeling choices, such as the use of parameter point estimates and assumption of simplistic toxicodynamic models, are largely unexplored.

Transplacental transfer of cobalt: Evidence from a study of mothers and their neonates in the African Copperbelt.

Background: Transfer of the trace metal cobalt (Co) from mother to foetus has not been documented in populations with high environmental exposure to Co, as is the case in the African Copperbelt mining region. We analysed data obtained from 246 mother-infant pairs included (at delivery) in a previously published case-control study on birth defects, done in Lubumbashi (Democratic Republic of Congo) between March 1, 2013, and Feb 28, 2015.

Methods: Co was measured by Inductively Coupled Plasma Mass Spectrometry in maternal blood, maternal urine, umbilical cord blood and placental tissue, as available.

Metal Mixture Toxicity of Ni, Cu, and Zn in Freshwater Algal Communities and the Correlation of Single-Species Sensitivities Among Single Metals: A Comparative Analysis.

The effects assessment of metals is mainly based on data of single metals on single species, thereby not accounting for effects of metal mixtures or effects of species interactions. Both of these effects were tested in combination, thereby hypothesizing that the sensitivity of a community to synergistic mixture toxicity depends on the correlation of single-species sensitivities among the single metals. Single-metal and metal-mixture effects were tested in full concentration-response experiments (fixed ray of 1:1:3 and 5:1:13 mass ratio Ni:Cu:Zn) on eight single freshwater algal species and 14 algal communities of four species each.

Monitoring cadmium concentrations in cacao: inter-laboratory variation and the effect of sample size on variability among ready-for-sale beans.

Since the implementation of new EU limits on cadmium (Cd) in cacao-derived products, reliable measurements of the Cd concentration in cacao samples have become even more important. This study was set up to analyse the robustness of the measured Cd concentrations in cacao as affected by sampling strategy and by the laboratory receiving these samples. Six different homogenised cacao liquor samples were sent to 25 laboratories, mainly located in Latin America.

Cadmium speciation in cacao beans changes during a fermentation-like incubation.

Cadmium (Cd) concentrations in cacao often exceed food limits. Recently, it was shown that cacao bean fermentation enhances Cd solubility, opening potential for Cd mitigation in cacao products. This study was set-up to identify changes in Cd speciation during fermentation.

Colloids facilitate cadmium and uranium transport in an undisturbed soil: A comparison of soil solution isolation methods.

Accurate data of cadmium (Cd) and uranium (U) leaching are needed in the context of identifying their mass balances in agricultural soils. There is some controversy related to sampling methods and the contribution of colloid facilitated transport. Here, leaching was measured in undisturbed unsaturated soils and the impact of colloids was measured with due attention to solution sampling protocols.

Screening redox stability of iron rich by-products for effective phosphate immobilisation in freshwater sediments.

Iron (Fe) rich by-products can be added to lake or river sediments to immobilise phosphate (PO) and lower eutrophication risks. These Fe materials differ in mineralogy and specific surface area, hence differing in PO sorption capacity and stability under reducing conditions. This study was set up to identify key properties of these amendments in their capacity to immobilise PO in sediments.

Soil amendments to reduce cadmium in cacao (Theobroma cacao L.): A comprehensive field study in Ecuador.

The new EU regulations on maximum levels of cadmium (Cd) in cacao products sparked research on countermeasures to reduce Cd concentrations in cacao beans. This study was set up to test the effects of soil amendments in two established cacao orchards (soil pH 6.6 and 5.

Bleeding Complications in a Patient After the Unexpected Interaction between Valproic Acid and Phenprocoumon.

Background: Phenprocoumon is a vitamin K antagonist that is widely prescribed in Europe and Latin America for the prophylaxis and treatment of thromboembolic events.

Case Presentation: A 90-year-old female was admitted to our hospital with tonic-clonic seizures, possibly due to dementia syndrome. Valproic acid (VPA) was prescribed for the treatment of seizures.

Quantitative clay mineralogy predicts radiocesium bioavailability to ryegrass grown on reconstituted soils.

Current radiocesium (Cs) models to evaluate the risk of Cs transfer from soil to plants are based on the clay and exchangeable potassium (K) contents in soil. These models disregard the mineralogy of the clay fraction and are likely not capable of accurately predicting the Cs transfer factor (TF) in soils of contrasting parent rocks and weathering stages. The objectives of this study were to test that hypothesis and to identify whether quantitative information on mineralogy can improve the predictions.