TiC MXene Modified with Ceramic Oxide and Noble Metal Nanoparticles: Synthesis, Morphostructural Properties, and High Photocatalytic Activity.

Among two-dimensional (2D) materials, such as graphene, a new family of 2D anisotropic carbides and nitrides of early transition metals (MXenes) is very interesting because of the potential applications in electronics, medicine, and photocatalysis. In this paper, preparation, morphostructural characterization, band gaps determination, and salicylic acid photodegradation ability of TiC MXene and six nanocomposites consisting of the MXene modified by TiO, AgO, Ag, PdO, Pd, and Au are reported. It was confirmed using electron diffraction studies, energy dispersive X-ray spectroscopy, and high-resolution transmission microscopy that metals and metal oxides occur on the MXene flakes as nanoparticles in a shape of spots.

Raman scattering studies on very thin layers of gallium sulfide (GaS) as a function of sample thickness and temperature.

Gallium sulfide is a semiconducting material with a layered structure and a characteristic low interlayer interaction. Because of weak van der Waals forces, GaS crystals are relatively easy to exfoliate to very thin layers. In this work nanometric-GaS layers were obtained by a micro-mechanical exfoliation process and were transferred to Si/SiO substrate.