Spectroscopic investigation of OCS (p-H(2))(n) (n=1-16) complexes inside helium droplets: Evidence for superfluid behavior.

Up to 16 parahydrogen and orthodeuterium molecules have been assembled around an OCS carbonyl sulfide chromophore molecule inside the pure (4)He and mixed (4)He(3)He droplets at temperatures of 0.38 and 0.15 K, respectively.

Effect of the symmetry of H2 molecules on their rotations around an OCS molecule in superfluid 4He droplets.

The infrared spectra of OCS-(H2)(n) clusters in cold (0.15 K) superfluid 4He droplets coated with 3He exhibit resolved rotational bands for each n up to n=8 para-H2 (pH(2)) or ortho-D2 (oD(2)) molecules. An analysis of the different Q-branch intensities based on the different spin symmetries of pH(2) and oD(2) indicates the formation of symmetric 5- or 6-membered rings around the linear carbonyl sulfide (OCS) chromophore.