The integration of polypyrrole (PPy) into bacterial cellulose (BC) has provided significant conductivity and cost benefits. However, this combination has led to a reduction in mechanical properties, particularly in terms of elongation at break and tensile strength. This study investigated the enhancement of BC/PPy composite films by incorporating polyvinyl alcohol (PVA).
View Article and Find Full Text PDFThermochromic textiles possess the capability to indicate ambient temperature through color changes, enabling real-time temperature monitoring and providing temperature warnings for body heat management. In this study, three thermochromic dyes-blue, red, and yellow-were synthesized using crystalline violet lactone (CVL), 6'-(diethylamino)-1',3'-dimethyl-fluoran (DDF), and 3',6'-dimethoxyfluoran (DOF) as leuco dyes, respectively, with biomass tea polyphenol serving as the color developer and tetradecanol as the phase change material. The chemical structures of these dyes were characterized using UV spectroscopy, infrared spectroscopy, Raman spectroscopy and H NMR.
View Article and Find Full Text PDFA conductive film (PNIPAM-rGO/BC) was fabricated combining bacterial cellulose (BC) with poly-N-isopropylacrylamide-modified graphene oxide (PNIPAM-GO) through vacuum filtration and steam reduction techniques. The conductivity and performance of PNIPAM-GO composite and the resulting conductive film were studied. The key findings revealed that PNIPAM-GO composite exhibited a reversible temperature-sensitive behavior.
View Article and Find Full Text PDFIn this study, we investigated the preparation and characterization of flexible conductive fiber membranes (BC/PPy) using different metal salt oxidants on bacterial cellulose (BC) and pyrrole (Py) in the in situ polymerization and co-blended methods, respectively. The effects of these oxidants, namely, ferric chloride hexahydrate (FeCl·6HO) and silver nitrate (AgNO), on the structural characterization, conductivity, resistance value and thermal stability of the resulting materials were assessed by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). A comparative study revealed that the BC/PPy conductive fiber membrane prepared using FeCl·6HO as the oxidant had a resistance value of 12 Ω, while the BC/PPy conductive fiber membrane prepared using AgNO as the oxidant had an electrical resistance value of 130 Ω.
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