Unique amorphous/crystalline heterophase coupling for an efficient oxygen evolution reaction.

Designing amorphous/crystalline heterophase catalysts is still in the initial stage, and the study of amorphous/crystalline heterophase and carbon-free catalysts has not yet been realized. Herein, we report a unique amorphous/crystalline heterophase catalyst consisting of NiFe alloy nanoparticles (NPs) supported on TiO (NiFe/TiO) for the first time, which is achieved by a heterophase supporting strategy of dual heat treatment. Surprisingly, the amorphous/crystalline heterophase is flexibly composed of amorphous and crystalline phases of alloy NPs and TiO.