L-cysteine capped silver nanoparticles as chiral recognition sensor for ketoprofen enantiomers.

A simple, inexpensive but effective approach for visual chiral recognition of ketoprofen enantiomers was developed using L-cysteine capped silver nanoparticles (L-Cys-AgNPs) as a colorimetric sensor. Upon the addition of R-ketoprofen to L-Cys-AgNPs, rapid aggregation occurred, and the solution changed color from yellow to green. However, the presence of S-ketoprofen did not induce any color change.

Spectroscopic studies for the inclusion complexation of ketoprofen enantiomers with β-cyclodextrin.

Inclusion complexes of R-ketoprofen and S-ketoprofen enantiomers with β-cyclodextrin (β-CD) in aqueous solution were studied using various spectroscopic techniques such as Raman, FTIR, UV and fluorescence. The different relative intensities and characteristic band shifts of the two enantiomers from Raman spectra suggests different interaction when complexed with β-CD. Raman experiments revealed a noticeable diminishing of the CC vibration and ring deformation, which indicate the embedding of ketoprofen inside the β-CD cavity.

Highly sensitive and selective determination of malathion in vegetable extracts by an electrochemical sensor based on Cu-metal organic framework.

This article demonstrates the first application of a copper-based porous coordination polymer (BTCA-P-Cu-CP) as a carbon paste electrode (CPE) modifier for the detection of malathion. The electrochemical behavior of BTCA-P-Cu-CP/CPE was explored using cyclic voltammetry (CV) while chrono-amperometry methods were applied for the analytical evaluation of the sensor performance. Under optimized conditions, the developed sensor exhibited high reproducibility, stability, and wide dynamic range (0.

Aqua-{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio-cyanate groups and one water mol-ecule. In the crystal, O-H⋯S hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H⋯π inter-actions.

(E)-N'-(5-Bromo-2-hy-droxy-benzyl-idene)-3,5-dihy-droxy-benzohydrazide monohydrate.

The Schiff base mol-ecule in the title compound, C(14)H(11)BrN(2)O(4)·H(2)O, is almost planar with an r.m.s.

3,4,5-Trihydr-oxy-N'-[(1-methyl-1H-indol-2-yl)methyl-idene]benzohydrazide.

The structure of the title compound, C(17)H(15)N(3)O(4), displays inter-molecular O-H⋯N and O-H⋯O hydrogen bonding between adjacent mol-ecules. Intra-molecular O-H⋯O hydrogen bonds also occur. The molecule is essentially planar with a deviation of 0.

N'-(2,4-Dimethoxy-benzyl-idene)-3,4,5-trihydroxy-benzohydrazide ethanol solvate.

The title compound, C(16)H(16)N(2)O(6)·C(2)H(5)OH, was synthesized from 3,4,5-trihydroxy-benzoyl-hydrazide and 2,4-dimethoxy-benzaldehyde in ethanol. The compound is not planar, with the two aromatic planes of the two aromatic rings twisted by 15.6 (1)°.

A second monoclinic polymorph of 2-(diformyl-methyl-idene)-3,3-dimethyl-2,3-dihydro-1H-indole.

The crystal structure of the title compound, C(13)H(13)NO(2), is a polymorph of the structure first reported by Helliwell et al. [Acta Cryst. (2006), E62, o737-o738].

[Bis(3-phenyl-prop-2-enyl-idene)propane-1,3-diamine-κN,N']dibromidocobalt(II).

In the crystal structure of the title compound, [CoBr(2)(C(21)H(22)N(2))], the Co(II) atom is four-coordinated by two bromide anions and two N atoms from the bidentate Schiff base ligand in a distorted tetra-hedral geometry.

N-[1-(2-Hydroxy-phen-yl)ethyl-idene]-N-(1H-indol-3-ylmethyl-ene)carbonic dihydrazide.

In the crystal structure of the title compound {alternative name: 1-[1-(2-hydroxy-phen-yl)ethyl-ideneamino]-3-(1H-indol-3-ylmethyl-eneamino)urea}, C(18)H(17)N(5)O(2), the planar indole component is twisted at an angle of 63.7 (10)° with respect to the rest of the mol-ecule. This compound is one of a series being studied for biological activity.