Miniaturized and wearable electronic products require electromagnetic interference shielding (EMI) materials with sensing functions to cope with complex application situations. Herein, an effective dual-network structure is designed to fabricate two-dimensional transition metal carbides and nitrides/bacterial cellulose-thermoplastic polyurethane (MXene/BC-TPU) foams with intriguing EMI shielding property and piezoelectric sensing ability under both compressive and tensile strains. Anisotropic MXene/BC aerogels, as conductive networks, with impressive conductivity (1912 S m), ultrahigh EMI shielding effectiveness (SE) of 86 dB, and absolute SE up to 63,608 dB cm g can be built by directional freezing.
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