Identification of key transcription factors from transcriptome data by correlating gene expression levels with transcription factor binding sites is important for transcriptome data analysis. In a typical scenario, we always set a threshold to filter the top ranked differentially expressed genes and top ranked transcription factor binding sites. However, correlation analysis of filtered data can often result in spurious correlations.
View Article and Find Full Text PDFCellular protein homeostasis is maintained by the disposal of aggregated misfolded proteins. Here, we present a protocol for investigating the involvement of the proteins of interest in misfolded protein degradation via Agrobacterium-mediated transient expression in Nicotiana benthamiana. We describe in detail the steps of misfolded protein design, transient protein expression in N.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2024
Transition metal metaphosphates and noble metal phosphides prepared under similar conditions are potential hybrid catalysts for electrocatalytic water splitting, which is of great significance for H production. Herein, the structure and electrocatalytic activity of different noble metal species (i.e.
View Article and Find Full Text PDFFacing with serious carbon emission issues, the production of green H from electrocatalytic hydrogen evolution reaction (HER) has received extensive research interest. Almost all kinds of noble metal phosphides (NMPs) consisting of Pt-group elements (i.e.
View Article and Find Full Text PDFIn this work, a new photovoltaic device was prepared. The device uses titanium (Ti) foil/TiO nanotubes as the photoanode and multi-walled carbon nanotubes (MWCNTs) as a photosensitizer. Titanium dioxide nanotube arrays (TiO-NTs) were prepared by one-step anodic oxidation.
View Article and Find Full Text PDFHere, a strategy to regulate the electron density distribution by integrating NiFe layered double hydroxides (NiFe-LDH) nanosheets with Co O nanowires to construct the NiFe-LDH/Co O p-n heterojunction supported on nickel foam (NiFe-LDH/Co O /NF) for electrocatalytic oxygen evolution reaction (OER) is proposed. The p-n heterojunction can induce the charge redistribution in the heterogeneous interface to reach Fermi level alignment, thus modifying the adsorption free energy of *OOH and improving the intrinsic activity of the catalyst. As a result, NiFe-LDH/Co O /NF exhibits outstanding OER performance with a low overpotential of 274 mV at a current density of 50 mA cm and long-time stability over 90 h.
View Article and Find Full Text PDFWater electrolysis affords a promising approach to large-scale hydrogen yield, but its efficiency is restrained by the sluggish water dissociation kinetics. Here, an efficient bifunctional electrocatalyst of in situ formed crystalline nickel metaphosphate on amorphous NiMoO nanoarrays supported on nickel foam (c-Ni P O /a-NiMoO /NF) for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline solution is reported. The c-Ni P O /a-NiMoO /NF can deliver a current density of 10 mA cm at a low potential of 78 mV for HER, and a current density of 20 mA cm at an overpotential of 250 mV for OER.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2021
In this work, titania (TiO) nanoparticles modified by Eu(TTA)Phen complexes (ETP) were prepared by a simple solvothermal method developing a fluorescence Mn pollutant sensing system. The characterization results indicate that the ETP cause structural deformation and redshifts of the UV-visible light absorptions of host TiO nanoparticles. The ETP also reduce the crystallinity and crystallite size of TiO nanoparticles.
View Article and Find Full Text PDFCo-based bimetallic metal-organic frameworks (MOFs) have emerged as a kind of promising electrocatalyst for oxygen evolution reaction (OER). However, most of present works for Co-based bimetallic MOFs are still in try-and-wrong stage, while the OER performance trend and the underlying structure-function relationship remain unclear. To address this challenge, Co-based MOFs on carbon cloth (CC) (CoM MOFs/CC, M = Zn, Ni, and Cu) are prepared through a room-temperature method, and their structure and OER performance are compared systematically.
View Article and Find Full Text PDFChem Commun (Camb)
June 2020
Herein, FeMoO nanorods are explored as an efficient electrocatalyst for nitrogen reduction reaction (NRR) in 0.1 M NaSO solution, with an NH yield rate of 17.51 μg h mg and a high faradaic efficiency (FE) of 10.
View Article and Find Full Text PDFAgarwood is a traditional and precious medicinal material and natural spice in China and other southeast Asian countries.As the head of all spices,agarwood has many pharmacological activities such as analgesia,antidiarrheal,anti-inflammatory and antibacterial effects. Due to its high price and scarce resources,there were just a few previous studies on it,mainly focusing on the chemical compositions of the agarwood essential oil and solvent extract mixture.
View Article and Find Full Text PDFChem Commun (Camb)
December 2019
Here we demonstrate the synthesis of uniform Ru-doped NiFe2O4 nanosheets with robust hydrogen evolution reaction (HER) activity in alkaline solution, with an extremely low overpotential of 18 mV versus a reversible hydrogen electrode (RHE) at a current density of 10 mA cm-2 and a Tafel slope of 27 mV dec-1.
View Article and Find Full Text PDFElectrocatalytic hydrogen evolution has attracted a great deal of attention due to the urgent need for clean energy. Herein, we demonstrate the synthesis of ternary pyrite-type cobalt phosphosulphide (CoPS) nanoparticles supported on a nitrogen-doped carbon matrix, CoPS/N-C, through carbonization and subsequent phosphosulfurization of Co-based zeolitic imidazolate frameworks (ZIF-67), as promising hydrogen evolution reaction (HER) electrocatalysts in both acidic and alkaline solutions. The polyhedral structure of ZIF-67 can be well maintained in the as-prepared CoPS/N-C nanocomposites.
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