Two Types of Liquid Phase Separation Induced by Soft Centrifugation in Aqueous Ethyl Acetate Using Ethanol as Cosolvent.

Water/ethyl acetate/ethanol is widely used as a "green" extractant system. We show that 2 different types of phase separation can be induced upon centrifugation in this ternary system using ethanol as a cosolvent of water and ethyl acetate: centrifuge-induced criticality and centrifuge-induced emulsification. The expected composition profiles of samples after centrifugation can be represented by bent lines in a ternary phase diagram when gravitational energy is added to the free energy of mixing.

Short-chain branched sulfosuccinate as a missing link between surfactants and hydrotropes.

Surfactants aggregate in water into micelles, and these micelles incorporate organic substances to solubilize them. Hydrotropes are compounds that increase the solubility of hydrophobic substances in water without this form of aggregation. Decreasing the chain length of the classical surfactant Aerosol OT (AOT) from C8 to C5 results in a molecule with intermediate properties.

Theory of Ternary Fluids under Centrifugal Fields.

In this work, we developed a general theoretical description of ternary solutions of small molecules under a centrifugal field, from which we obtained the centrifugation map (CMap) as a general tool to understand observations or to predict composition profiles in centrifugal fields of arbitrary strength. The theoretical formalism is based on the classical density functional theory with established models for liquid mixtures. Thermodynamics also yields a general criterion for apparent aggregation.