High-Entropy Metal-Organic Frameworks and Their Derivatives: Advances in Design, Synthesis, and Applications for Catalysis and Energy Storage.

As a nascent class of high-entropy materials (HEMs), high-entropy metal-organic frameworks (HE-MOFs) have garnered significant attention in the fields of catalysis and renewable energy technology owing to their intriguing features, including abundant active sites, stable framework structure, and adjustable chemical properties. This review offers a comprehensive summary of the latest developments in HE-MOFs, focusing on functional design, synthesis strategies, and practical applications. This work begins by presenting the design principles for the synthesis strategies of HE-MOFs, along with a detailed description of commonly employed methods based on existing reports.

Printed High-Entropy Prussian Blue Analogs for Advanced Non-Volatile Memristive Devices.

Non-volatile memristors dynamically switch between high (HRS) and low resistance states (LRS) in response to electrical stimuli, essential for electronic memories, neuromorphic computing, and artificial intelligence. High-entropy Prussian blue analogs (HE-PBAs) are promising insertion-type battery materials due to their diverse composition, high structural integrity, and favorable ionic conductivity. This work proposes a non-volatile, bipolar memristor based on HE-PBA.

Using the High-Entropy Approach to Obtain Multimetal Oxide Nanozymes: Library Synthesis, Structure-Activity, and Immunoassay Performance.

High-entropy nanomaterials exhibit exceptional mechanical, physical, and chemical properties, finding applications in many industries. Peroxidases are metalloenzymes that accelerate the decomposition of hydrogen peroxide. This study uses the high-entropy approach to generate multimetal oxide-based nanozymes with peroxidase-like activity and explores their application as sensors in bioassays.

Operando acoustic emission monitoring of degradation processes in lithium-ion batteries with a high-entropy oxide anode.

In recent years, high-entropy oxides are receiving increasing attention for electrochemical energy-storage applications. Among them, the rocksalt (CoCuMgNiZn)O (HEO) has been shown to be a promising high-capacity anode material. Because high-entropy oxides constitute a new class of electrode materials, systematic understanding of their behavior during ion insertion and extraction is yet to be established.

Monitoring of Thermally Induced Effects in Nickel-Rich Layered Oxide Cathode Materials at the Atomic Level.

The thermal stability of cathode active materials (CAMs) is of major importance for the safety of lithium-ion batteries (LIBs). A thorough understanding of how commercially viable layered oxide CAMs behave at the atomic length scale upon heating is indispensable for the further development of LIBs. Here, structural changes of Li(NiCoMn)O (NCM851005) at elevated temperatures are studied by aberration-corrected scanning transmission electron microscopy (AC-STEM).

Lithium containing layered high entropy oxide structures.

Layered Delafossite-type Li(MMMMM…M)O materials, a new class of high-entropy oxides, were synthesized by nebulized spray pyrolysis and subsequent high-temperature annealing. Various metal species (M = Ni, Co, Mn, Al, Fe, Zn, Cr, Ti, Zr, Cu) could be incorporated into this structure type, and in most cases, single-phase oxides were obtained. Delafossite structures are well known and the related materials are used in different fields of application, especially in electrochemical energy storage (e.

The Role of Intragranular Nanopores in Capacity Fade of Nickel-Rich Layered Li(NiCoMn)O Cathode Materials.

Ni-rich layered LiNiCoMnO (NCM, + ≤ 0.2) is an intensively studied class of cathode active materials for lithium-ion batteries, offering the advantage of high specific capacities. However, their reactivity is also one of the major issues limiting the lifetime of the batteries.

Silicon Nanoparticles with a Polymer-Derived Carbon Shell for Improved Lithium-Ion Batteries: Investigation into Volume Expansion, Gas Evolution, and Particle Fracture.

Silicon (Si) and composites thereof, preferably with carbon (C), show favorable lithium (Li) storage properties at low potential, and thus hold promise for application as anode active materials in the energy storage area. However, the high theoretical specific capacity of Si afforded by the alloying reaction with Li involves many challenges. In this article, we report the preparation of small-size Si particles with a turbostratic carbon shell from a polymer precoated powder material.