Transparent TiO nanotubes supporting silver sulfide for photoelectrochemical water splitting.

Differences between photoelectrochemical and electrochemical activity were thoroughly investigated for the oxygen evolution reaction mediated by AgS deposited on two types of ordered titania substrates. Titanium dioxide nanotubes were fabricated by anodization of magnetron sputtered Ti films on ITO-coated glass substrates or directly from Ti foil. Further, AgS deposition on the nanotubes was carried out using successive ionic layer adsorption and reaction, known as SILAR, with 5, 25, and 45 cycles performed.