Nowadays trace metal contamination within urban atmospheres is a significant and concerning global issue. In the present study, two synanthropic bird species, namely, the feral pigeon ( f. ) and the rook (), were employed as bioindicators to assess the atmospheric trace metal pollution in Iasi City, Romania.
View Article and Find Full Text PDFThis work studies the technological preparation conditions, morphology, structural characteristics and elemental composition, and optical and photoluminescent properties of GaSe single crystals and Eu-doped -GaO nanoformations on -GaSe:Eu single crystal substrate, obtained by heat treatment at 750-900 °C, with a duration from 30 min to 12 h, in water vapor-enriched atmosphere, of GaSe plates doped with 0.02-3.00 at.
View Article and Find Full Text PDFOn the 23rd of September 2022, a small intensive aquaculture unit populated with rainbow trout () reported increased mortality in adults and juvenile fish. The unit comprised 12 enclosed concrete basins with a capacity of ten cubic meters of water, populated with 150 kg of fish each. Fish were subjected to a clinical examination on the site, after which whole fish were harvested for a bacteriological and histopathological examination.
View Article and Find Full Text PDFDual-pulsed (DPL) laser deposition using oyster shells as targets was studied in order to find out if this method can replace the use of high-power pulsed lasers. Aspects related to changes in the morphological structure of the thin layer but also to the chemical composition of the obtained thin layer were analyzed and compared with the target as well as with the thin layers obtained with a higher power pulsed laser in a single-pulsed (SPL) regime. Orthorhombic structures were noticed with Scanning Electron Microscopy for the thin film obtained in DPL mode compared to the irregular particles obtained in SPL mode.
View Article and Find Full Text PDFGaSSe solid solutions are layered semiconductors with a band gap between 2.0 and 2.6 eV.
View Article and Find Full Text PDFTiO-SiO nanocomposite thin films have gained the attention of the scientific community due to their unique physical and chemical properties. In this paper, we report on the fabrication and characterization of a TiO-SiO nanocomposite disk-shaped target. The target was used for the deposition of TiO-SiO nanocomposite thin films on fluorine-doped tin oxide/glass substrates using the pulsed laser deposition (PLD) technique.
View Article and Find Full Text PDFThe study in this paper was carried out as a result of the observation of pollution phenomena and foaming effects associated with anthropogenic activities, including street cleaning activity. The processes of dust binding used in order to reduce PM10 and PM 2.5 pollution has been proven to be inefficient, and even contributing to pollution with particulate matter.
View Article and Find Full Text PDFThe study in this paper presents a new material that was produced as a thin film by the Pulsed Laser Deposition technique (PLD) using a 532 nm wavelength and 150 mJ/pulse laser beam on the hemp stalk as target. The analyses performed by spectroscopic techniques (Fourier Transform Infrared Spectroscopy-FTIR, Laser-Induced Fluorescence Spectroscopy-LIF, Scanning Electron Microscopy coupled with Energy Dispersive X-ray-SEM-EDX, Atomic Force Microscopy-AFM and optical microscope) evidenced that a biocomposite consisting of lignin, cellulose, hemicellulose, waxes, sugars and phenolyc acids -coumaric and ferulic, similar to the hemp stalk target was obtained. Nanostructures and aggregated nanostructures of 100 nm to 1.
View Article and Find Full Text PDFCeramic thin films with variable thicknesses have been used in many applications. In order to protect the petroleum transportation pipes against the harmful HS action, two ceramic materials as thin layers are proposed. In this article, pulsed laser deposition (PLD) of ceramic layers by in situ time-resolved optical techniques is investigated.
View Article and Find Full Text PDFIn this work, optical, including photoluminescence and photosensitivity, characteristics of micrometer-sized flexible ()-InSe/InO heterojunctions, obtained by heat treatment of single-crystalline InSe plates doped with (0.5 at.%) Cd (Sn), in a water-vapor- and oxygen-enriched atmosphere, are investigated.
View Article and Find Full Text PDFHigh-power laser irradiation interaction with natural polymers in biocomposites and Laser-Induced Chitin Deacetylation (LICD) was studied in this work, in order to produce thin films consisting of chitosan composite. The new method can lead to a cutting-edge technology, as a response to the concern regarding the accumulation of "natural biological waste" and its use. The process consists of high-power laser irradiation applied on oyster shells as the target and deposition of the ablated material on different substrates.
View Article and Find Full Text PDFPossible implications and consequences of using SL(2R) as invariance groups in the description at any scale resolution of the dynamics of any complex system are analyzed. From this perspective and based on Jaynes' remark (any circumstance left unspecified in the description of any complex system dynamics has the concrete expression in the existence of an invariance group), in the present paper one specifies such unspecified circumstances that result directly from the consideration of the canonical formalism induced by the SL(2R) as invariance group. It follows that both the Hamiltonian function and the Guassian distribution acquire the status of invariant group functions, the parameters that define the Hamiltonian acquire statistical significances based on a principle of maximizing informational energy, the class of statistical hypotheses specific to Gaussians of the same average acts as transitivity manifolds of the group (transitivity manifolds which can be correlated with the multifractal-non-multifractal scale transitions), joint invariant functions induced through SL(2R) groups isomorphism (the SL(2R) variables group, and the SL(2R) parameters group, etc.
View Article and Find Full Text PDFThe aim of this in vitro study was to evaluate the effect of hydrochloric acid associated with the abrasive effect of toothbrushing on the surface condition of three flowable composite resins used for direct restoration. Seventy samples of each composite resin: Grandio Flow (VOCO, Germany)-group A, Filtek Ultimate Flow (3M-ESPE, MN, USA)-group B, G-aenial Flo X (GC Europe)-group C were prepared, submersed in hydrochloric acid 30% for 60 min and then submitted to simulated toothbrushing procedure using 5000 cycles with toothbrushes with medium and hard bristles, immediately after the chemical attack, after 30 min or without any chemical attack. The sample's surface roughness was analyzed using a noncontact profilometer (Dektak XT, Bruker, USA).
View Article and Find Full Text PDFIn the study presented in this paper, the results obtained by producing nanocomposites consisting of a silver citrate thin layer deposited on hemp fiber surfaces are analyzed. Using the pulsed laser deposition (PLD) method applied to a silver target with impurities of nickel and iron, the formation of the silver citrate film is performed in various ways and the results are discussed based on Fourier Transform Infrared (FTIR) and Scanning Electron Microscopy coupled with Energy Dispersive X-ray (SEM-EDX) spectroscopy analyses. A mechanism of the physico-chemical processes that take place based on the FTIR vibrational modes and the elemental composition established by the SEM-EDS analysis is proposed.
View Article and Find Full Text PDFGe-Sb-Te thin films were obtained by ns-, ps-, and fs-pulsed laser deposition (PLD) in various experimental conditions. The thickness of the samples was influenced by the Nd-YAG laser wavelength, fluence, target-to-substrate distance, and deposition time. The topography and chemical analysis results showed that the films deposited by ns-PLD revealed droplets on the surface together with a decreased Te concentration and Sb over-stoichiometry.
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