Sonochemical Synthesis of Magnetite/Poly(lactic acid) Nanocomposites.

Nanocomposites based on poly(lactic acid) (PLA) and magnetite nanoparticles (MNP-FeO) show promise for applications in biomedical treatments. One key challenge is to improve the stabilization and dispersion of MNP-FeO. To address this, we synthesized MNP-FeO/PLA nanocomposites using ultrasound mediation and a single iron(II) precursor, eliminating the need for surfactants or organic solvents, and conducted the process under ambient conditions.

Polymers Based on PLA from Synthesis Using D,L-Lactic Acid (or Racemic Lactide) and Some Biomedical Applications: A Short Review.

Poly(lactic acid) (PLA) is an important polymer that is based on renewable biomass resources. Because of environmental issues, more renewable sources for polymers synthesis have been sought for industrial purposes. In this sense, cheaper monomers should be used to facilitate better utilization of less valuable chemicals and therefore granting more sustainable processes.

Cerium-zirconium mixed oxide nanostructures for diesel soot oxidation: synthesis and effect of structure.

Nanostructured materials have been used in several branches of science and technology. Particulate matter is one of the major air pollution concerns. In this work, nanorods and nanoparticles of CeZrO (CZ) mixed oxides were prepared by different routes, and the use of an organic template was evaluated in diesel soot oxidation.

Niobium on BEA Dealuminated Zeolite for High Selectivity Dehydration Reactions of Ethanol and Xylose into Diethyl Ether and Furfural.

In this work, we investigated the role of solid-state dealumination by (NH)SiF (25% Al removal and 13% Si insertion), the impregnation of niobium (10, 18, and 25 wt. %) on dealuminated *BEA (DB) zeolite and their catalytic properties in ethanol and xylose transformations. Among all the studied catalysts, 18%Nb-DB showed increased mesoporosity and external areas.

Tuning the Biginelli reaction mechanism by the ionic liquid effect: the combined role of supported heteropolyacid derivatives and acidic strength.

Herein, a combination of heteropolyacids and ionic liquids as a catalytic system was studied for the Biginelli multicomponent reaction; the positive ionic liquid effect associated with the acidic strength of zeolite-supported heteropolyacids made this combination an efficient catalytic system for the multicomponent synthesis of 3,4-dihydropyrimidin-2(1)-one/thione derivatives. The acidic strength effect was evaluated, and a range was determined in which the reaction provided better results. The mechanism of the reaction was also investigated in the presence and absence of ionic liquids, and two features of paramount importance were revealed: the mechanism could be tuned to proceed through only one reaction path among three possibilities and the kinetics of the reaction was significantly faster in the presence of an ionic liquid.

Corrigendum to "Preparation of PLA blends by polycondensation of D,L-lactic acid using supported 12-tungstophosphoric acid as a heterogeneous catalyst" [Heliyon 5 (5) (May 2019) e01810].

[This corrects the article DOI: 10.1016/j.heliyon.

Preparation of PLA blends by polycondensation of D,L-lactic acid using supported 12-tungstophosphoric acid as a heterogeneous catalyst.

Poly(lactic acid) (PLA) is a significant polymer that is based on renewable biomass resources. The production of PLA by polycondensation using heterogeneous catalysis is a focus for sustainable and economical processes. A series of samples comprising 12-tungstophosphoric acid (HPW) supported on activated carbon, silica, and alumina induced the catalytic polymerization of D,L-lactic acid to form blends of PLA.

Analytical evaluation of BEA zeolite for the pre-concentration of polycyclic aromatic hydrocarbons and their subsequent chromatographic analysis in water samples.

The analytical performance of BEA - a commercial zeolite - is evaluated for the pre-concentration of fifteen Environmental Protection Agency - polycyclic aromatic hydrocarbons and their subsequent HPLC analysis in tap and lake water samples. The pre-concentration factors obtained with BEA have led to a method with excellent analytical figures of merit. One milliliter aliquots were sufficient to obtain excellent precision of measurements at the parts-per-trillion concentration level with relative standard deviations varying from 4.

Indirect determination of dichlorodiphenyltrichloroethane (DDT) after dechlorination with magnesium/palladium bimetallic particles and potentiometric measurements.

Determination of chlorine ions of pesticides was performed after dechlorination reaction using a palladium/magnesium system. Chlorine ions were quantified by potentiometry with ion-specific electrode. Rates of dechlorination of 100 microg of DDT as a function of reaction time and percent (wt/wt) of palladium deposited on the magnesium particles were determined.

Comparative adsorption studies of indigo carmine dye on chitin and chitosan.

The adsorption of indigo carmine dye onto chitin and chitosan from aqueous solutions was followed in a batch system. The ability of these materials to adsorb indigo carmine dye from aqueous solution was followed through a series of adsorption isotherms adjusted to a modified Langmuir equation. The maximum number of moles adsorbed was 1.

Calorimetric studies of the association of chitin and chitosan with sodium dodecyl sulfate.

The interaction of hydrophobic chitin and chitosan with sodium dodecyl sulfate (SDS) has been studied by titration calorimetry at 298.15K. The nature of interaction of the surfactant and biopolymers was followed by enthalpy interaction profiles.