Shanghai Kou Qiang Yi Xue
December 2023
A Zr-based metal-organic framework (Zr-MOF) which has free carbonyl groups is synthesized successfully through mix-ligand strategy. Subsequently, Tb is encapsulated into a Zr-MOF by postcoordinated modification. The Tb@Zr-MOF exhibits the characteristic emission of Tb because of efficient sensitization through antenna effects.
View Article and Find Full Text PDFA new class of Ln-MOFs (Ln = Eu, Tb, Eu/Tb, Sm) are synthesized through a post-synthetic modification of the parent MOF, UMCM-NH2. The luminescence spectra of Eu-MOF, Tb-MOF and Eu/Tb-MOF exhibit the characteristic emission bands of ligands and corresponding Ln3+, particularly Eu3+. Multi-color luminescence could be modulated by adjusting the excitation wavelength of the Eu-MOF and Tb-MOF.
View Article and Find Full Text PDFPhenylamine has been recognized as one of the most important industrially relevant ingredient and a crucial intermediate in chemical products. Yet, its internal exposure detection in human remains largely elusive due to the lack of potent monitoring method. Hereby this issue is addressed with a probe based on lanthanide functionalized organic-inorganic hybrid material Al(OH)(bpydc) (1) through post-synthetically modified metal-organic framework.
View Article and Find Full Text PDFZhonghua Er Bi Yan Hou Tou Jing Wai Ke Za Zhi
October 2012
Objective: To observe the travel, divisions, and the lengths, diameters, branches, artery supplies of the main segments of maxillary nerve.
Methods: Fifty formalin-preserved adult half-head specimens with intravascular injection of red color emulsion were used for the gross and microanatomical studies of maxillary nerve. The lengths, diameters, branches and artery supplies of four main segments of maxillary nerve were observed.