Progress in process parameters and mechanism research of polymer emulsion preparation.

As a new type of concrete admixture, polymer emulsion is mainly used to strengthen the properties of concrete by adhesion and physical and chemical crosslinking with cement in concrete. Under the background of construction in the new era, it is of great significance to elucidate all aspects of concrete performance under the action of polymer emulsion. In this paper, the main formation process of polymer emulsion is reviewed, the influence of synthetic materials required for polymerization on the polymerization process is discussed, and the regulating effects of reaction temperature, reaction time, admixtures, and treatment methods on the synthesis process of polymer emulsion are analyzed.

Synthesis and Modification of Polycarboxylate Superplasticizers-A Review.

The molecular-scale structural changes in polycarboxylic superplasticizer (PCE) can influence dispersion and water retention. Polycarboxylate superplasticizer, synthesized using different methods, may alter dispersion and water-reducing effects. The synthesis of PCE involves creating a novel macromolecular monomer with a controllable molecular mass, adjustable lipophilic, and hydrophilic moieties, as outlined in this study.

Investigation of the Effects of Polyurethane-Modified Polycarboxylate at Ambient Temperature on the Characteristics of Cement with Supplementary Cementitious Materials.

Via radical polymerization, three polyurethane-modified polycarboxylate molecules of various comb topologies were synthesized. This study investigated the effects of varying types and concentrations of supplementary cementitious materials (SCMs) on the surface tension, flowability, and zeta potential of cement. An elevation in the molar ratio between isoamyl alcohol polyoxyethylene (TPEG) and acrylic acid (AA) from 1:1 to 5:1 reduced the surface tension of the polycarboxylate molecule from 47.

Bubble Evolution under the Action of Polycarboxylate and Air-Entraining Agent and Its Effects on Concrete Properties-A Review.

In order to improve the performance of concrete, it is of great significance to have a better understanding the mechanism and main influencing factors of concrete bubble evolution under the action of polycarboxylate and air-entraining agents. In the present review, with respect to the generation, growth, stability, and rupture of concrete bubbles under the action of polycarboxylate and air-entraining agents, this paper discusses the influence of bubble characteristics on concrete performance and studies bubble regulation by air-entraining agents and polycarboxylate (PCE) superplasticizer. The results show that the acid-to-ether ratio, sulfonic acid group, ester group, and the type of air entraining agent of the polycarboxylate acid structure have a significant impact on the bubbles.