18.117.192.20518.117.192.205
In this work, the preparation of dense blended membranes, from blends of poly(vinylidene fluoride) (PVDF), poly(ether sulfone) (PES) and polyethyleneimine (PEI) or Fumion, with possible applications in alkaline fuel cell (AEMFC) is reported. The blended PEI/Fumion membranes were prepared under a controlled air atmosphere by a solvent evaporation method, and were characterized regarding water uptake, swelling ratio, thermogravimetric analysis (TGA), infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), ion exchange capacity (IEC), OH conductivity and novel hydroxide ion exchange rate (HIER), which is related to the mass transport capacity of the OH ions through the membrane. The effect of the chemical composition on its morphological and anion exchange properties was evaluated.
View Article and Find Full Text PDFThe effect of the nature of the catalyst on the performance and mechanism of the hydrogen oxidation reaction (HOR) is discussed for the first time in this work. HOR is an anodic reaction that takes place in anionic exchange membrane fuel cells (AEMFCs) and hydrogen pumps (HPs). Among the investigated catalysts, Pt exhibited the best performance in the HOR.
View Article and Find Full Text PDFIn the present work, chemically modified graphene oxide (GO) was incorporated as a crosslinking agent into thin-film composite (TFC) nanofiltration (NF) membranes for water desalination applications, which were prepared by the interfacial polymerization (IP) method, where the monomers were piperazine (PIP) and trimesoyl chloride (TMC). GO was functionalized with monomer-containing groups to promote covalent interactions with the polymeric film. The composite GO/polyamide (PA) was prepared by incorporating amine and acyl chloride groups into the structure of GO and then adding these chemical modified nanomaterial during IP.
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