Recent update on the electroactive oligopyrrolic macrocyclic hosts with a Bucky-ball heart.

Supramolecular chemistry is a multidisciplinary research area mostly associated with the investigation of host-guest interactions within intricate three-dimensional (3D) molecular architectures held together reversibly by various non-covalent interactions. Continuous efforts to develop such kinds of complex host-guest systems with designer oligopyrrolic macrocyclic receptors are a rapidly growing research domain, which is deeply involved in applied supramolecular chemistry research. These host-guest supramolecular complexes can be constructed by combining suitable electron-rich oligopyrrolic donors (as a host) with complementary electron-poor guests (as acceptors), held together by the ionic force of attraction triggered by intermolecular charge/electron transfer (CT/ET) transitions.

Molecular Rotors for the Detection of Chemical Warfare Agent Simulants.

The fluorogenic probe o-OH is able to detect and quantify organophosphorus nerve agent mimics in solution and in the vapor phase following immobilization on a solid substrate, making the system a suitable candidate for the field detection of chemical warfare agents. Detection is achieved by the suppression of internal rotation upon phosphorylation of a reactive phenolate, resulting in a large fluorescence "turn-on" response.