Publications by authors named "Shu-ping Sun"

Electrolysis of carbon dioxide (CO2) in acid offers a promising route to overcome CO2 loss in alkaline and neutral electrolytes, but requires concentrated alkali cations (typical ≥3 M) to mitigate the trade-off between low pH and high hydrogen evolution reaction (HER) rate, causing salt precipitation. Here we report a strategy to resolve this problem by introducing tensile strain in a copper (Cu) catalyst, which can selectively reduce CO2 to valuable multicarbon products, particularly ethylene, in a pH 1 electrolyte with 1 M potassium ions. We find that the tension-strained Cu creates an electron-rich surface that concentrates diluted potassium ions, contributing to CO2 activation and HER suppression.

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Article Synopsis
  • Seawater electrolysis for hydrogen production using renewable electricity is promising, but suffers from slow electrode performance and durability issues.
  • A new molybdenum nitride (MoN) catalyst shows comparable efficiency to commercial platinum in seawater, lasting over 1000 hours without degradation, while platinum experiences significant issues after just 36 hours.
  • The MoN catalyst improves performance by generating ammonium groups at its surface, which stabilize local conditions and reduce pH fluctuations, and it operates effectively in a membrane flow electrolyzer setting, achieving high performance over extended times.
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Reduction of carbon dioxide (CO) by renewable electricity to produce multicarbon chemicals, such as ethylene (CH), continues to be a challenge because of insufficient Faradaic efficiency, low production rates, and complex mechanistic pathways. Here, we report that the rate-determining steps (RDS) on common copper (Cu) surfaces diverge in CO electroreduction, leading to distinct catalytic performances. Through a combination of experimental and computational studies, we reveal that C─C bond-making is the RDS on Cu(100), whereas the protonation of *CO with adsorbed water becomes rate-limiting on Cu(111) with a higher energy barrier.

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Three new species of Mesoleptidea Viereck, 1912: M. nigra Li & Sun, sp. nov.

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Carbon-carbon coupling electrochemistry on a conventional copper (Cu) catalyst still undergoes low selectivity among many different multicarbon (C) chemicals, posing a grand challenge to achieve a single C product. Here, we demonstrate a laser irradiation synthesis of a gerhardtite mineral, Cu(OH)NO, as a catalyst precursor to make a Cu catalyst with abundant stacking faults under reducing conditions. Such structural perturbation modulates electronic microenvironments of Cu, leading to improved d-electron back-donation to the antibonding orbital of *CO intermediates and thus strengthening *CO adsorption.

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Background: Elevated low-density lipoprotein cholesterol (LDL-C) is an established risk factor for atherosclerotic cardiovascular disease (ASCVD). However, low adherence to medication and lifestyle management has limited the benefits of lowering lipid levels. Cognitive behavioral therapy (CBT) has been proposed as a promising solution.

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Two new species of Alcochera (Ichneumonidae, Ctenopelmatinae, Mesoleiini), Alcochera flavoclypeata Sheng Sun, sp. nov. collected from Labagoumen Natural Reserve, Huairou, Beijing, and A.

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The genus Microstenus Szépligeti, 1916 (Hymenoptera: Ichneumonidae: Cryptinae) is newly recorded from China based on a new species, Microstenus rufithorax Sheng, Li Sun, sp. nov., collected from Guangxi Zhuang Autonomous Region, Oriental part of China.

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Five species of the genus Ozols are reported. One, Sheng & Li, collected from Liaoning province, China, is new to science. In addition, digital images and a taxonomic key to the all species of are presented.

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A new species, Sheng, , and two new records for China, (Uchida, 1952) and Uchida, 1930, collected in Mentougou, Beijing, belonging to the tribe Mesoleiini of the subfamily Ctenopelmatinae (Hymenoptera, Ichneumonidae), are reported. A key to the six species of known from China is given.

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Background: Branchio-oto-renal (BOR) syndrome is a dominant autosomal disorder characterized by phenotypes such as hearing loss, branchial fistulae, preauricular pits, and renal abnormalities. EYA1, the human homolog of the Drosophila "eye absent" gene on chromosome 8q13.3, is recognized as one of the most important genes associated with BOR syndrome.

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A new genus, Verruca Sheng Sun gen. nov., of the ichneumonid tribe Atrophini, subfamily Banchinae is described for one new species, Verruca dentia Sheng Sun, sp.

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A new species of Eulophinae, Li & Yang, , is described and illustrated. This new species is a larval ectoparasitoid of Xu (Lepidoptera, Eriocraniidae), a leaf miner in birch trees, spp. (Betulaceae), in Qinghai Province, northwest China.

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A new species of Poemeniinae, Sun & Sheng, , is described and illustrated. Specimens were reared from twigs of Blume in Haicheng, Liaoning province, P.R.

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Combivena Sheng & Sun, gen.n. and Combivena sulcata Sheng & Sun, sp.

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A new species, Notopygus longiventris Sun & Sheng, sp. n., collected from Benxi County, Liaoning Province, China, and N.

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A new species, Amphibulus melanarius Zong, Sun & Sheng, sp.n., belonging to the tribe Phygadeuontini of the subfamily Cryptinae (Hymenoptera: Ichneumonidae), collected from Beijing, China, is reported.

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Six species of the genus Aptesis Förster 1850 belonging to the tribe Hemigastrini of the subfamily Cryptinae (Hymenoptera, Ichneumonidae) are reported from China. Three of them, Aptesis elongata Li & Sheng, sp. n.

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Larvae of the argid sawfly, Arge pullata (Zaddach) (Hymenoptera: Argidae), feeds on leaves of birch (Betula spp.) in China, Europe, Siberia, and Japan. Parasitoids of A.

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Four species of the genus Lamachus Förster 1869 belonging to the tribe Mesoleiini of the subfamily Ctenopelmatinae (Hymenoptera, Ichneumonidae) are reported from China. Two of them are new to science, Lamachus nigrus Li, Sheng & Sun, sp. n.

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A new species is described, Xorides benxicus Sheng, sp. n., reared from the cerambycid twig-boring pest of Robinia pseudoacacia Linnaeus, Pterolophia alternata Gressitt, 1938, in Benxi County, Liaoning Province, China.

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A new species, Syntactus jiulianicus Sun & Sheng, sp.n. belonging to the tribe Pionini of the subfamily Ctenopelmatinae (Hymenoptera, Ichneumonidae), collected from Jiangxi Province, China, is reported.

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Three species of Ateleute Förster 1869 belonging to the tribe Cryptini of the subfamily Cryptinae (Hymenoptera, Ichneumonidae), collected from Jiangxi Province, China, are reported, of which two are new for science: Ateleute ferruginea Sheng, Broad & Sun, sp. n. and AAteleute zixiensis Sheng, Broad & Sun, sp.

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A new species, Cisaris canaliculatus Sun & Sheng, sp. n., belonging to the tribe Phygadeuontini of the subfamily Cryptinae (Hymenoptera: Ichneumonidae), collected from Jiangxi Province, China, is reported.

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