One new pyridine-3,4-dicarboxylhydrazidate-coordinated compound [Zn(pdh)] 1 (pdh = pyridine-3,4-dicarboxylhydrazidate) was obtained under the hydrothermal conditions. Noteworthily, the pdh molecules in the title compound originated from the ligand in situ reaction between organic pyridine-3,4-dicarboxylic acid (pdca) and NH·HO. X-ray single-crystal diffraction analysis revealed that the pdh ligands exhibit a special μ-bridging mode in compound 1, which link Zn(II) centers into a 2D layered structure.
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