Self-Assembled Nano-Filamentous Zeolite Catalyst to Realize Efficient One-Step Ethanol Synthesis.

The non-petroleum synthesis route of ethanol from syngas (H +CO) with methyl acetate (MA) as the core intermediate product has been confirmed as an excellent industrialization route for high purity ethanol production. However, as the central part of this tandem-catalysis path, the carbonylation of dimethyl ether (DME) to MA is limited by the undesirable catalytic activity and stability of zeolite catalysts. Herein, a facile inhibitor-assisted strategy was developed for constructing self-assembled nano-Mordenite (nano-MOR) zeolites without using any expensive or complex template.

Ammonia pools in zeolites for direct fabrication of catalytic centers.

Reduction process is a key step to fabricate metal-zeolite catalysts in catalytic synthesis. However, because of the strong interaction force, metal oxides in zeolites are very difficult to be reduced. Existing reduction technologies are always energy-intensive, and inevitably cause the agglomeration of metallic particles in metal-zeolite catalysts or destroy zeolite structure in severe cases.

A Carbonylation Zeolite with Specific Nanosheet Structure for Efficient Catalysis.

Up to now, the member of zeolite family has expanded to more than 230. However, only little part of them have been reported as catalysts used in reactions. Discovering potential zeolites for reactions is significantly important, especially in industrial applications.