Purpose: Colonic perforation is a life-threatening complication after colonic stent insertion as a bridge to surgery for acute obstruction caused by colorectal cancer. The oncological consequence of colonic perforation after emergent surgical intervention was unknown. The aim of this short communication was to investigate whether or not the perforation and emergent surgery had obviously impact on the peritoneal recurrence and long-term survival of patients.
View Article and Find Full Text PDFPhys Chem Chem Phys
May 2011
The H → D isotopic substitution of the hydroxylic hydrogen participating in the O-H···O hydrogen bond in the tert-butylalcohol dimer produces an increase of the B and C rotational constants, according to the shrinkage of the OO distance of about 7 mÅ, underlying and sizing the associated Ubbelohde effect.
View Article and Find Full Text PDFWe investigated the rotational spectra of six isotopologues of pyridine--Ne(2), formed by combinations of two isotopes of the nitrogen atom ((14)N and (15)N) in pyridine with two isotopes of the rare gas atoms ((20)Ne and (22)Ne), by using pulsed jet Fourier transform microwave spectroscopy. We detected the C(2v) symmetry conformer, denoted as [1,1], where the Ne atoms are located one on each side of the ring plane. The [2,0] species, with the two Ne atoms on the same side of the ring, was not observed.
View Article and Find Full Text PDFTo study the effects of ovariectomy on tumorigenesis and microsatellite instability (MSI) in rat colon tumors induced by 1,2-dimethylhydrazine, to elucidate the association between postmenopausal ovarian hormones depletion and MSI pathway in colorectal tumorigenesis. Forty female Wistar rats were randomly divided into two groups: Ovariectomized (Ovx) group and Sham-ovariectomized (Sham-Ovx) group. All rats were injected intraperitoneally with 1,2-dimethylhydrazine (DMH) (20 mg/kg b.
View Article and Find Full Text PDFThe rotational spectra of six isotopologues of pyridine-xenon, two isotopes of the nitrogen atom ((14)N and (15)N) in pyridine with three isotopes of the rare gas atom ((129)Xe, (131)Xe, and (132)Xe) have been measured by pulsed jet Fourier transform microwave spectroscopy. The complex has a structure with the xenon atom located in the plane of symmetry perpendicular to the aromatic ring plane. Its distance from the center of mass of pyridine is 3.
View Article and Find Full Text PDFA novel method of inline coupling of microdialysis (MD) with CE has been investigated. A polysulfone MD membrane was in situ prepared at the inlet end of the separation capillary, which endued the capillary with an additional function of clean-up sampling and made the pretreatment of complex matrices simple. The properties of the membrane and its influence on electrophoresis were evaluated.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
April 2004
Surface analysis methods for structure and characters of silane film on metal surface were reviewed in this paper. Many instrumental methods, such as XPS, ATR-FTIR, RA-FTIR, SIMS, ellipsometry, EIS and so on, were applied to characterizing different silane films on different metal base surfaces. According to the research on silane film formation mechanism, silane film state, silane film structure, silane film thickness, silane film corrosion resistance and so on, factors which affect silane film properties were discussed.
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