Atomically Dispersed Cu in Zeolitic Imidazolate Framework Nanoflake Array for Dendrite-Free Zn Metal Anode.

Aqueous Zn metal batteries (AZMBs) have been considered as a promising alternative to the existing Li-ion batteries. Nevertheless, the large-scale application of the AZMBs is restricted by the dendrite formation and side reactions within the Zn metal anodes (ZMAs) during cycling. Herein, an atomically dispersed Cu in leaf-like Zn-coordinated zeolitic imidazolate framework (ZIF-L) nanoflakes on Ti mesh (CuZIF-L@TM) as ZMA host is developed.