Successive Phase Transition, Dielectric Ordering, and Liquid Crystalline Behavior of Simple (Laurylammonium)(Phenyl Phosphates) Salts.

Successive phase transitions of three kinds of simple 1:1 organic salts of laurylammonium (LA)-phenyl (3-pyridyl) phosphate derivative were examined in terms of thermal properties, single crystal X-ray structural analyses, powder X-ray diffractions, and dielectric responses, where the phosphate anion was chemically modified from phenylphosphate (1) and 3-pyridylphosphate (2) to m-fluorophosphate (3). All 1:1 simple organic salts showed the successive solid-solid and solid-smectic A (SmA) phase transition with high thermal stability. Isostructural alternate cation-anion layer was observed in LA-1 and LA-2, and the packing structure of LA-3 was different from those of the former salts.

Conformational Transformations of (C12H25NH3(+))(Pyridinesulfonate) in the Solid State.

The phase-transition behaviors, crystal structures, and dielectric properties of four kinds of simple 1:1 organic salts of (C12H25NH3(+))(benzenesulfonate) and (C12 H25NH3(+))(pyridine sulfonates) were examined from the viewpoint of intermolecular hydrogen-bonding interactions and dynamic conformational transformation in molecular assemblies. Crystals of (C12H25NH3(+))(benzenesulfonate) and (C12H25NH3(+))(3-pyridinesulfonate) were isostructural and solid-solid and solid-liquid-crystal smectic A (SmA) phase transitions were observed. These two crystals formed rodlike cation-anion assemblies.