Nanofibrillar hydrogels are an important class of biomaterials with applications as catalytic scaffolds, artificial extracellular matrixes, coatings, and drug delivery materials. In the present work, we report the results of a comprehensive study of nanofibrillar hydrogels formed by cellulose nanocrystals (CNCs) in the presence of cations with various charge numbers and ionic radii. We examined sol-gel transitions in aqueous CNC suspensions and the rheological and structural properties of the CNC hydrogels.
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