Recent advancements in materials design have driven the scientific community to explore phosphor materials for multifunctional applications. This study presents the multimodal light emission (downshifting - DS, quantum cutting - QC, and upconversion - UC) from Pr/Yb activated NaLa(MoO) phosphors for multifunctional applications. Under blue (449 nm) and NIR (980 nm) excitation, co-doped phosphors emit visible light through DS and UC processes caused by different f-f transitions of Pr ions.
View Article and Find Full Text PDFMAPK pathway regulates the major events including cell division, cell death, migration, invasion, and angiogenesis. Small molecules that modulate the MAPK pathway have been demonstrated to impart cytotoxicity in cancer cells. Herein, the synthesis of a new isoxazolyl-urea derivative (QR-4) has been described and its effect on the growth of pancreatic cancer cells has been investigated.
View Article and Find Full Text PDFWe report electromagnetic interference (EMI) shielding efficiency in the PANI-wrapped BaFeO and SrFeO with rGO composites. Barium and strontium hexaferrites were synthesized using the nitrate citrate gel combustion method. These hexaferrites were polymerized with aniline.
View Article and Find Full Text PDFIn the present study, the binding affinity of 52 bioactive secondary metabolites from towards the anti-apoptotic B-cell lymphoma-2 (Bcl-2) protein (PDB: 2W3L) structure was identified by using in silico molecular docking and molecular dynamics simulation. The molecular docking results demonstrated that the binding energies of docked compounds with Bcl-2 protein ranged from -5.3 kcal/mol to -10.
View Article and Find Full Text PDFIn the present study, we have synthesized a series of Dy3+ ion doped NaLa(MoO4)2phosphors by the conventional solid-state method at 750 °C for 4h. All the compounds were crystallized in the tetragonal scheelite type structure with space group (I41/a, No.88).
View Article and Find Full Text PDFCladosporium spp. have been reported for their great diversity of secondary metabolites which represent as a prominent base material for verifying the biological activities. Several bioactive compounds which have antimicrobial, cytotoxic, quorum sensing inhibitory and phytotoxic activities have been isolated from Cladosporium species.
View Article and Find Full Text PDFThe present study deals with the synthesis of SrTiO (STO) nanocatalysts by conventional oxalate and microwave-assisted hydrothermal methods. Thorough characterization of the nanocatalysts synthesized has been done by using various techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy, N physisorption, transmission electron microscopy, total acidity by pyridine adsorption method, and acidic strength by -butylamine potentiometric titration, respectively. Structural parameters were estimated by Rietveld refinement analysis from XRD data which confirms cubic structure of SrTiO.
View Article and Find Full Text PDFRed light emitting cubic ZrEuO:Li (0-9 mol%) nanoparticles are synthesized by a low temperature, self-propagating solution combustion method using oxalyl di-hydrazide (ODH) as fuel. In this study, we report systematic investigation of the effect of lithium ion (Li) concentration on the structural properties and the photoluminescence of zirconia. With increasing lithium concentration, the crystallinity of the samples increases and the lattice strain decreases.
View Article and Find Full Text PDFArtif Cells Nanomed Biotechnol
May 2017
In this work, we designed an amperometric catechol biosensor based on α-FeO nanocrystals (NCs) incorporated carbon-paste electrode. Laccase enzyme is then assembled onto the modified electrode surface to form a nanobiocomposite enhancing the electron transfer reactions at the enzyme's active metal centers for catechol oxidation. The biosensor gave good sensitivity with a linear detection response in the range of 8-800 μM with limit of detection 4.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2015
Eu(3+)-activated BaMoO4 phosphors were synthesized by the nitrate-citrate gel combustion method. The Rietveld refinement analysis confirmed that all the compounds were crystallized in the scheelite-type tetragonal structure with I41/a (No. 88) space group.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
June 2015
CeO2:Ho(3+) (1-9 mol%) nanopowders have been prepared by efficient and environmental friendly green combustion method using Aloe vera gel as fuel for the first time. The final products are well characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), fourier transform infrared (FTIR). Bell, urchin, core shell and flower like morphologies are observed with different concentrations of the A.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2015
One-dimensional (1D) zinc oxide (ZnO) hexagonal rods have been successfully synthesized by surfactant free hydrothermal process at different temperatures. It can be found that the reaction temperature play a crucial role in the formation of ZnO uniform hexagonal rods. The possible formation processes of 1-D ZnO hexagonal rods were investigated.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2015
Ceramic luminescent powders with the composition Ca(0.96-x)Eu0.04Bi(x)SiO3 (x=0.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2015
Stolzite polymorph of PbWO4 catalyst was prepared by the facile room temperature precipitation method. Structural parameters were refined by the Rietveld analysis using powder X-ray data. PbWO4 was crystallized in the scheelite-type tetragonal structure with space group I41/a (No.
View Article and Find Full Text PDFA modified solution combustion approach was applied in the synthesis of nanosize SrFeO(3-δ) (SFO) using single as well as mixture of citric acid, oxalic acid, and glycine as fuels with corresponding metal nitrates as precursors. The synthesized and calcined powders were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis and derivative thermogravimetric analysis (TG-DTG), scanning electron microscopy, transmission electron microscopy, N2 physisorption methods, and acidic strength by n-butyl amine titration methods. The FT-IR spectra show the lower-frequency band at 599 cm(-1) corresponds to metal-oxygen bond (possible Fe-O stretching frequencies) vibrations for the perovskite-structure compound.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2015
Novel crystalline tetragonal ZrO2: Eu(3+) phosphors were prepared by a facile and efficient low temperature solution combustion method at 400±10 °C using oxalyl dihydrazide (ODH) as fuel. The powder X-ray diffraction patterns and Rietveld confinement of as formed ZrO2: Eu(3+) (1-11 mol%) confirmed the presence of body centered tetragonal phase. The crystallite size estimated from Scherrer's and W-H plots was found to be in the range of 7-17 nm.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2014
GdAlO3, GdAlO3:Eu(3+) and GdAlO3:Eu(3+):Bi(3+) nanophosphors were synthesised by solution combustion technique. Pure orthorhombic phase was obtained from powder X-ray diffraction (PXRD) studies. Scanning electron microscopy (SEM) micrographs showed the porous, agglomerated and irregular shaped particles.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2014
ZnO:Eu (0.1 mol%) nanopowders have been synthesized by auto ignition based low temperature solution combustion method. Powder X-ray diffraction (PXRD) patterns confirm the nanosized particles which exhibit hexagonal wurtzite structure.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2014
Cobalt copper ferrite nanopowders with composition Co1-xCuxFe2O4 (0.0≤x≤0.5) was synthesized by solution combustion method.
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July 2014
CaTiO3:Sm(3+) (1-11 mol%) nanophosphors were successfully synthesized by a low temperature solution combustion method [LCS]. The structural and morphological properties of the phosphors were studied by using Powder X-ray diffractometer (PXRD), Fourier transform infrared (FTIR), X-ray photo electron spectroscopy (XPS), scanning electron microscope (SEM) and transmission electron microscopy (TEM). TEM studies indicate that the size of the phosphor is ∼20-35 nm.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
July 2014
Gd(1.96-x)Y(x)Eu0.04O3 (x = 0.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
July 2014
This work explores the preparation of nanocrystalline Cr(3+) (1-5 mol%) doped CaSiO3 phosphors by solution combustion process and study of its photoluminescence (PL) behavior. The nanopowders are well characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Fourier transform infra-red (FTIR) spectroscopy. PXRD results confirm monoclinic phase upon calcination at 950°C for 3h.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2014
Pure cubic zirconia (ZrO2) nanopowder is prepared for the first time by simple low temperature solution combustion method without calcination. The product is characterized by Powder X-ray Diffraction (PXRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Fourier Transform Infra Red spectroscopy (FTIR) and Ultraviolet-Visible spectroscopy (UV-Vis). The PXRD showed the formation of pure stable cubic ZrO2 nanopowders with average crystallite size ranging from 6 to 12 nm.
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