Self-Assembled Interlayer Enables High-Performance Organic Photovoltaics with Power Conversion Efficiency Exceeding 20.

Interfacial layers (ILs) are prerequisites to form the selective charge transport for high-performance organic photovoltaics (OPVs) but mostly result in considerable parasitic absorption loss. Trimming the ILs down to a mono-molecular level via the self-assembled monolayer is an effective strategy to mitigate parasitic absorption loss. However, such a strategy suffers from inferior electrical contact with low surface coverage on rough surfaces and poor producibility.

Balancing the Selective Absorption and Photon-to-Electron Conversion for Semitransparent Organic Photovoltaics with 5.0% Light-Utilization Efficiency.

Efficiently converting invisible light while allowing full visible light transmission is key to achieving high-performance semitransparent organic photovoltaics (ST-OPVs). Here, a detailed balance strategy is explored to optimize the ST-OPV via taking both absorption and carrier dynamics into consideration. Based on this principle, comprehensive optimizations are carried out, including a ternary strategy, donor:acceptor blend ratio, thickness, antireflection, etc.