Publications by authors named "Shikun Li"

Article Synopsis
  • - This study presents a new method called the Prins tandem approach for efficiently producing isoprene from renewable sources like bio-based methanol and isobutene using specialized catalysts.
  • - The research highlights how hydration changes the catalyst properties, specifically increasing OH groups, which enhances isoprene selectivity and boosts methanol conversion rates to 90% and 92%.
  • - Additionally, the catalysts demonstrate strong recycling capabilities, maintaining a 90% selectivity for isoprene after multiple uses, while theoretical calculations show that hydration helps lower energy barriers in the chemical reactions involved.
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Learning from crowds describes that the annotations of training data are obtained with crowd-sourcing services. Multiple annotators each complete their own small part of the annotations, where labeling mistakes that depend on annotators occur frequently. Modeling the label-noise generation process by the noise transition matrix is a powerful tool to tackle the label noise.

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Composed query image retrieval task aims to retrieve the target image in the database by a query that composes two different modalities: a reference image and a sentence declaring that some details of the reference image need to be modified and replaced by new elements. Tackling this task needs to learn a multimodal embedding space, which can make semantically similar targets and queries close but dissimilar targets and queries as far away as possible. Most of the existing methods start from the perspective of model structure and design some clever interactive modules to promote the better fusion and embedding of different modalities.

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Neonatal genital prolapse is a rare situation. This report presents a unique case involving a pair of premature female twins who both developed vaginal wall prolapse without any neurological deficits. Multiple factors such as selective intrauterine growth restriction, feeding intolerance, extrauterine growth retardation, and elevated intra-abdominal pressure after birth may have contributed to the development of this phenomenon.

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Heat accumulation generated from confined space poses a threat to the service reliability and lifetime of electronic devices. To quickly remove the excess heat from the hot spot, it is highly desirable to enhance the heat dissipation in a specific direction. Herein, we report a facile route to fabricate the large-scale composite film with enhanced thermal conductivity and electrical insulation.

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The rich surface chemistry of gold at the nanoscale has made it an important catalyst for low-temperature applications. Recent studies point to the possible role of self-organized structures formed by chemisorbed O atoms on the surface of gold catalysts for their catalytic activity and/or deactivation. In this study, we investigate the reactivity of a double O chain running along a step on a Au(221) surface with oxygen vacancies as a prototypical model of a 1D surface gold oxide.

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Anuran amphibians are susceptible to infection by intestinal nematodes, but the damage and response mechanisms that occur in their intestines after infection are only partially understood. In this study, the intestinal disruption and response mechanisms in Amolops wuyiensis frogs infected with Cosmocercoides wuyiensis n. sp.

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Microbial infections have become a great threat to human health and one of the main risks arises from direct contact with the surfaces contaminated by pathogenic microbes. Herein, a kind of hexagonal column interpenetrated spheres (HCISs) are fabricated by non-covalent assembly of plant gallic acid with quaternary ammonium surfactants. Different from one-time burst release of conventional antimicrobial agents, the HCIS acts like a "antimicrobial molecular bank" and releases the antimicrobial ingredients in a multistage way, leading to long-lasting antimicrobial performance.

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The clinical application of the artificial intelligence-assisted system in imaging was investigated by analyzing the magnetic resonance imaging (MRI) influence characteristics of cerebral infarction in critically ill patients based on the convolutional neural network (CNN). Fifty patients with cerebral infarction were enrolled and examined by MRI. Besides, a CNN artificial intelligence system was established for learning and training.

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Background: Systematic studies on the development and adaptation of hindlimb muscles in anura amphibians are rare. Here, we integrated analysis of transcriptome and histomorphological data for the hindlimb thigh muscle of Odorrana tormota (concave-eared torrent frog) at different developmental stages, to uncover the developmental traits of hindlimb thigh muscle from O. tormota and its adaptability to different life history stages.

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Promotion of crop yield by compost application is generally thought to be ascribed to a better supply of macro and micronutrients, however the importance of compost DOM on plant growth has not been well demonstrated. In this study, composting of chicken manure, spent mushroom and sawdust was conducted under aerobic or anaerobic condition to determine the effects of compost DOM on plant growth. It was found that dissolved organic matter (DOM) first increased and then decreased in compost, and DOM of anaerobic compost was slightly higher than that of aerobic compost.

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Rare earth oxides are attracting increasing interest as a relatively unexplored group of materials with potential applications in heterogeneous catalysis and electrocatalysis; therefore, a credible and universal computational approach is needed for modeling their reactivity. In this work, we systematically assessed the performance of the PBE+U method against the results of the hybrid HSE06 method with respect to the description of structural parameters and energetic properties of the selected hexagonal lanthanide sesquioxides and the cubic fluorite-type cerium dioxide. In addition, we evaluated the performance of PBE+U in describing the electronic structure and adsorption properties of the CeO(111) and NdO(0001) surfaces.

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In some countries, snakes are important protein sources in human diets, and their economic value depends predominantly on their muscle production, including in the king ratsnake (Elaphe carinata). Muscle growth in the king ratsnake clearly differs among individuals. To date, few potential molecular mechanisms underlying these differences in muscle growth and development have been reported.

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Recent deep trackers have shown superior performance in visual tracking. In this article, we propose a cascaded correlation refinement approach to facilitate the robustness of deep tracking. The core idea is to address accurate target localization and reliable model update in a collaborative way.

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Efficient catalysis of the methanol oxidation reaction (MOR) greatly determines the widespread implementation of direct methanol fuel cells. Exploring a suitable support for noble metal catalysts with regard to decreasing the mass loading and optimizing the MOR activity remains a key challenge. Herein, we achieve an over 60% activity enhancement of a palladium (Pd) catalyst by introducing a two-dimensional TiCT MXene as the support compared to a commercial Pd/C catalyst.

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Several studies have previously observed surprisingly low frequencies for the C-H stretching modes of self-assembled monolayers (SAMs) prepared from aromatic thiols. The reason for this property has so far remained elusive. Therefore, we report a novel study of the vibrational spectra of SAMs prepared on Au from two different aromatic thiols, namely, 4'-nitro-1,1'-biphenyl-4-thiol (NBPT) and 4-aminothiophenol (ATP).

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Direct synthesis of renewable p-xylene (PX) by cycloaddition of biomass-derived 2,5-dimethylfuran (2,5-DMF) and ethylene was achieved over Al-rich H-beta zeolites synthesized by an organotemplate-free approach and their dealuminated counterparts with different Si/Al ratios. Among them, H-beta zeolite with an Si/Al ratio of 22, obtained from an Al-rich parent by dealumination, was found to be an excellent catalyst for the synthesis of PX. A PX yield of 97 % and 2,5-DMF conversion of 99 % were obtained under optimized conditions.

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The literature of social class and inequality is not only diverse and rich in sight, but also complex and fragmented in structure. This article seeks to map the topic landscape of the field and identify salient development trajectories over time. We apply the Latent Dirichlet Allocation topic modeling technique to extract 25 distinct topics from 14,038 SSCI articles published between 1956 to 2017.

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Here we utilized Al MAS/MQMAS and P MAS NMR of quantitative adsorption of trimethylphosphine oxide (TMPO) and DFT calculations to elucidate the relationship between Al distribution and Brönsted acidity of series H-Beta zeolites derived from dealumination of Al-rich H-Beta zeolite. Three types of Brönsted acid strengths corresponding to different specific Al T-sites were demonstrated. The removal of one framework Al in 5MR2--2Al and 6MR-2Al sites led to increasing the Brönsted acid strength of dealuminated H-Beta.

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An amphibious robot with straight compliant flipper-legs can conquer various amphibious environments. The robot can rotate its flipper-legs and utilize their large deflection to walk on rough terrain, and it can oscillate the straight flipper-legs to propel itself underwater. This paper focuses on the dynamics of the compliant straight flipper-legs during terrestrial locomotion by modeling its deformation dynamically with large deflection theory and simulating it to investigate the parameters of locomotion such as trajectory, velocity, and propulsion.

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The asymmetric unit of the title compound, C(12)H(16)O(2), contains two independent mol-ecules in which the dihedral angles between the benzene and cyclo-propane rings are 75.9 (3) and 76.3 (3)°.

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Four new transition metal complexes (Habtz)(2)[M(DCA)(2)]·6H(2)O (M=Co(II) (1), Ni(II) (2), Cu(II) (3), Zn(II) (4); DCA=demethylcantharate, 7-oxabicyclo [2.2.1]heptane-2,3-dicarboxylate, C(8)H(8)O(5); Habtz=2-aminobenzothiazole acid, C(7)H(7)N(2)S) were synthesized and characterized by elemental analysis, molar conductance, infrared spectra and thermogravimetric analysis.

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In the title compound, C(16)H(15)N(3)O(3), the dihedral angle between the approximately planar benzimidazolyl group (r.m.s.

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The title compound, {[Cd(C(8)H(8)O(5))(C(10)H(8)N(2))]·H(2)O}(n), was obtained by the reaction of cadmium acetate with 2,2'-bi-pyridine and 7-oxabicyclo-(2.2.1)heptane-2,3-dicarb-oxy-lic anhydride.

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In the crystal structure of the title salt, (C(7)H(7)N(2)S)(2)[Co(C(8)H(8)O(5))(2)]·6H(2)O, the heterocyclic N atom of the 2-amino-benzothia-zole mol-ecule is protonated. The Co(II) atom is situated on an inversion centre and exhibits a slightly distorted octa-hedral CoO(6) coordination defined by the bridging O atoms of the bicyclo-heptane unit and four carboxyl-ate O atoms of two symmetry-related and fully deprotonated ligands. The crystal packing is stabilized by N-H⋯O hydrogen bonds between the cations and anions and by O-H⋯O hydrogen bonds including the crystal water mol-ecules.

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