Significant influence of urban human activities and marine input on rainwater chemistry in a coastal large city, China.

The coastal urban region is generally considered an atmospheric receptor for terrestrial and marine input materials, and rainfall chemistry can trace the wet scavenging process of these materials. Fast urbanization in China's east coastal areas has greatly altered the rainwater chemistry. However, the chemical variations, determinants, and sources of rainfall are unclear.

Chemical evolution of rainfall in China's first eco-civilization demonstration city: Implication for the provenance identification of pollutants and rainwater acid neutralization.

Rainfall chemistry is a vital indicator for reflecting anthropogenic/natural input on atmospheric quality, and the rainfall process is also the main sink of air contaminants, which has received widely concerns by all walks of life. However, the chemical compositions, sources of major solutes, historical evolution, and their determinants of rainwater in Chinese urban area, which is hotspot of atmospheric pollutant emission, are unclear under the dual background of fast economic development and eco-civilization construction. To decipher these issues, the latest year data of observation-based rainwater chemistry and the historical rainwater data, and air pollution data of China's first eco-civilization demonstration city were integrated and studied.

Flat edge modes of graphene and of Z2 topological insulator.

A graphene nano-ribbon in the zigzag edge geometry exhibits a specific type of gapless edge modes with a partly flat band dispersion. We argue that the appearance of such edge modes are naturally understood by regarding graphene as the gapless limit of a Z2 topological insulator. To illustrate this idea, we consider both Kane-Mele (graphene-based) and Bernevig-Hughes-Zhang models: the latter is proposed for HgTe/CdTe 2D quantum well.