Borohydride-Scaffolded Li/Na/Mg Fast Ionic Conductors for Promising Solid-State Electrolytes.

Borohydride solid-state electrolytes with room-temperature ionic conductivity up to ≈70 mS cm have achieved impressive progress and quickly taken their place among the superionic conductive solid-state electrolytes. Here, the focus is on state-of-the-art developments in borohydride solid-state electrolytes, including their competitive ionic-conductive performance, current limitations for practical applications in solid-state batteries, and the strategies to address their problems. To open, fast Li/Na/Mg ionic conductivity in electrolytes with BH groups, approaches to engineering borohydrides with enhanced ionic conductivity, and later on the superionic conductivity of polyhedral borohydrides, their correlated conductive kinetics/thermodynamics, and the theoretically predicted high conductive derivatives are discussed.

Amorphous Li2 O2 : Chemical Synthesis and Electrochemical Properties.

When aprotic Li-O2 batteries discharge, the product phase formed in the cathode often contains two different morphologies, that is, crystalline and amorphous Li2 O2 . The morphology of Li2 O2 impacts strongly on the electrochemical performance of Li-O2 cells in terms of energy efficiency and rate capability. Crystalline Li2 O2 is readily available and its properties have been studied in depth for Li-O2 batteries.