Publications by authors named "Shi-hua Qi"

Abscisic acid (ABA) and ethylene are two essential hormones that play crucial roles throughout the entire plant life cycle and in their tolerance to abiotic or biotic stress. In recent decades, increasing research has revealed that, in addition to their individual roles, these two hormones are more likely to function through their interactions, forming a complex regulatory network. More importantly, their functions change and their interactions vary from synergistic to antagonistic depending on the specific plant organ and development stage, which is less focused, compared and systematically summarized.

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Determining the differences in flower hydraulic traits and structural resource allocation among closely related species adapted to low mean annual precipitation (MAP) can provide insight into plant adaptation to arid environments. Here, we measured the maximum flower hydraulic conductance (K), water potential at induction 50% loss of K (P), flower pressure-volume parameters, dry mass of individual flowers and structural components (vexillum, wings, keels, stamens and sepals) of six Caragana species growing in regions ranging from 110 to 1400 mm MAP. Compared with species from high-MAP environments, those from low-MAP environments presented lower K, more negative P, osmotic potential at full turgor (π) and turgor loss points (π), and a greater bulk modulus of elasticity (ε).

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-nitrosamines are a type of nitrogen-containing organic pollutant with high carcinogenicity and mutagenicity. In the main drinking water sources of small and medium-sized towns in China, the contamination levels of -nitrosamines remain unclear. In addition, there is still lack of research on the concentration of -nitrosamines and their precursors in tributary rivers.

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Conventional chemical extraction methods may lead to overestimate or underestimate bioaccessibility due to their inability to provide realistic kinetic information regarding PAHs in soils. In this study, we propose the use of magnetic solid phase extraction (MSPE) technique for assessing the bioaccessibility of PAHs in the soil-earthworm system. Firstly, a novel polydopamine-coated magnetic core-shell microspheres (FeO-CPDA) was developed by a one-pot sol-gel and self-polymerization method.

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  • The study analyzed hourly datasets of particulate matter (PM) mass concentration and its chemical composition during the 7th Military World Games in Wuhan, focusing on changes before, during, and after the event due to local control measures.
  • Results showed a 14.7% decrease in PM mass concentration during the control period, alongside an increase in secondary components like sulfate and nitrate, indicating a shift in pollution sources.
  • After the control measures ended, humidity dropped, leading to a 36.9% decrease in secondary components, while mineral element concentrations surged, suggesting ongoing challenges with pollution management despite reduced industrial and coal emissions.
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Karst wetland plays an important role in the ecological environment; however, due to the existence of karst pipeline, pollutants can threaten the underground environment through the highly developed karst pipeline. Therefore, understanding the pollution characteristics of the karst surface environment is the premise of pollution ecological risk assessment and prevention. In this study, 24 organochlorine pesticides (OCPs) were analyzed to study the concentration, composition, source, and risk of OCPs in water and surface sediments in the Huixian Wetland of Guilin.

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The hourly concentrations of 102 volatile organic compounds (VOCs) in Wuhan from June to July in 2019 were obtained using an online monitoring instrument. The (VOCs) varied from 24.9 to 254 μg·m, with a mean value of (67.

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In order to understand the pollution characteristics, spatial distribution, potential sources, and ecological risk of heavy metals in the sediments of Tangxun Lake, the contents of heavy metals (As, Hg, Cd, Cr, Cu, Pb, Zn, and Ni) in the surface sediments of Tangxun Lake were analyzed, and the pollution status and potential ecological risk degree of heavy metals in the sediments were evaluated using the geo-accumulation index and potential ecological risk index. The potential sources of heavy metal pollutants were analyzed by correlation and principal component analysis. The results showed that except for Cr, the contents of other heavy metals were higher than their background values.

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  • * Pingdingshan showed the highest concentration of water-soluble ions, attributed to biomass combustion in rural regions, while the urban Wuhan and suburban Suizhou had lower concentrations.
  • * Sulfate, nitrate, and ammonium ions were predominant in all locations, with PM characteristics varying: alkaline in Wuhan and Pingdingshan, weakly acidic in Suizhou, influenced by local sources and secondary conversion processes.
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  • China faces significant winter fine particle (PM) pollution, particularly in Wuhan, influenced by regional air mass transportation.
  • Using a positive matrix factorization model, the study identified real-time PM sources and found major contributors include secondary inorganic aerosol (34.1%), vehicular exhaust (23.7%), and coal combustion (11.5%).
  • The analysis indicated diurnal variations in source contributions, with iron and steel production peaking in the morning and vehicular exhaust showing notable patterns during the day and night.
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  • Frequent haze episodes in the Fenwei Plain have worsened air quality, especially during winter and holidays, due to coal combustion, industrial emissions, and geographical factors.
  • Air samples taken in Linfen during the Spring Festival revealed that the average concentration of sulfur dioxide (SO) exceeded national air quality limits, indicating it as the main pollutant, while nitrogen oxides (NO) and carbon monoxide (CO) were influenced by nearby urban areas.
  • Analysis suggests that the basin topography of the Fenwei Plain significantly contributes to haze formation, with potential pollution sources identified mainly in Northern Shaanxi, Southern Gansu, and Southern Ningxia, influenced by the region's monsoon climate.
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  • * Results revealed that zinc concentrations were the highest, with arsenic and cadmium levels exceeding China’s air quality standards, indicating potential health risks, particularly during peak haze conditions.
  • * A health risk assessment highlighted that children are at higher risk for non-carcinogenic health effects from metal exposure compared to adults, with lead specifically identified as a non-carcinogenic risk for children, while adult exposure posed no significant risks.
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This study provides data and theoretical support for the prevention and control of air pollution in central China. From January 13, 2018, to January 25, 2018, 48 PM samples were collected in Huanggang by particulate matter samplers during a severe pollution episode. Twelve elements (Li, Be, V, Se, Sr, Mo, Ag, Ba, Tl, Th, Bi, and U) were analyzed by ICP-MS.

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  • Wood and economic crops are commonly used in rural China, but their combustion releases volatile organic compounds (VOCs) which haven't been extensively studied.
  • The study simulated the burning of various woods and crop straws in a lab, collecting and analyzing the emitted VOCs using advanced gas chromatography techniques.
  • Results highlighted significant differences in VOC compositions across different biomass types, identifying key compounds like ethylene, toluene, and propionaldehyde that contribute to ozone formation potential (OFP) from burning.
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This study investigates the elemental characteristics and sources of aerosol fine particulate matter (PM) samples obtained from Pingdingshan, Suizhou, and Wuhan, Central China, in June 2017. Thirteen kinds of elements (Ti, Zn, Cu, Cr, As, Pb, Fe, Ni, Se, V, Sb, Cd, and Co) were analyzed by inductively coupled plasma mass spectrometry (ICP-MS), and three source identification methods-enrichment factor, principle component analysis and multiple linear regression (PCA-MLR), and backward trajectory clustering-were applied. The results showed that Zn was the highest trace element in PM in samples from Pingdingshan, Suizhou, and Wuhan, and that the concentration of As exceeded the annual limit of Chinese air quality standards (GB 3096-2012).

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Due to the trace levels of polycyclic aromatic hydrocarbons (PAHs) in soil and the complexity of soil matrices, effective sample pretreatment methods are of great significance to obtain accurate analytical results. In this paper, polydopamine (PDA) encapsulated FeO particles were used as seeds for in situ polymerization of divinylbenzene (DVB) to derive magnetic hybrid material FeO@PDA@PDVB. Coupled with pressurized liquid extraction, FeO@PDA@PDVB was investigated as a selective adsorbent for the extraction and cleanup of PAHs in soil.

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Bioaccessibility measurements of polycyclic aromatic hydrocarbons (PAHs) in soils are significant for exposure risk assessment. The current physicochemical methods require tedious operation processes, underestimate the actual risks, or are unsuitable for high organic content soils. In this work, an efficient and convenient method based on polydopamine-coated polyethylene sieve plate (PDA@PESP) and hydroxypropyl-β-cyclodextrin (HPCD) was developed to predict the bioaccessibility of PAHs in multi-type soils.

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  • The study investigates the use of metal-organic frameworks (MOFs) as materials to clean up polycyclic aromatic hydrocarbons (PAHs) in soil, specifically looking at four different types of MOFs.
  • MIL-101(Cr) was found to be the most effective adsorbent for purifying sixteen different PAHs, influenced by factors like metal ion type and pore size.
  • The developed method, which includes ultrasonic extraction and gas chromatography with mass spectrometry, achieved a significant reduction in matrix effects and allows for the detection of PAHs at very low concentrations, showing good agreement with established EPA methods.
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Seventeen soil samples were collected along the main stream of the Hanjiang River in April 2013. Thirteen types of organochlorine pesticides (OCPs) were detected in the samples by gas chromatography with a Ni electron capture detector. The purpose of this study was to investigate the distribution, composition, and source of OCPs and assess the potential health risks for local residents.

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  • A novel phenyl-modified magnetic mesoporous silica (FeO@mSiO-Ph-PTSA) was synthesized using p-toluenesulfonic acid (PTSA) as a catalyst to improve the extraction of polycyclic aromatic hydrocarbons (PAHs) from complex soil samples.
  • The PTSA-catalyzed material showed a higher amount of phenyl functional groups and greater extraction efficiency for PAHs compared to a control sample synthesized without PTSA.
  • The study optimized extraction parameters and demonstrated that the new method had excellent detection limits and reduced matrix effects, outperforming traditional silica gel column methods for analyzing PAHs in soils.
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Ten sampling points were distributed approximately equidistantly in the Dajiuhu lake wetland, and soils from the depths 0-10 cm, 10-20 cm, and 20-30 cm were collected in April 2012. Gas chromatography-mass spectrometry (GC-MS) was used to analyze the remote mountain wetland shallow soils, and 16 kinds of USEPA priority controlled polycyclic aromatic hydrocarbon (PAH) pollutants were identified. The ∑PAHs content ranges of the shallow soils of this region were 48.

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Concentrations of volatile organic compounds (VOCs) in ambient air of a typical petrochemical industry park were measured using an on-line monitor (TH-300B) from December 2014 to February 2015. The composition, temporal variations, sources, and photochemical reactivity of VOCs were analyzed. Alkanes were the most abundant VOC species and contributed to 86.

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  • An online monitoring system measured volatile organic compounds (VOCs) in the air of a petrochemical industrial park during autumn 2014, revealing higher VOC levels compared to other cities.
  • Alkanes were the most prevalent type of VOC, with little change in their levels over the three months, though diurnal variations were noted for different VOC groups.
  • The main sources of VOCs were identified as natural gas transportation and solvent use, particularly from leaks and oil refining, with alkenes and alkanes being the most significant contributors based on reactivity analysis.
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A time-saving method was applied to synthesize methyltrimethoxy-modified magnetic mesoporous silica with or without p-toluenesulfonic acid as the catalyst for magnetic solid-phase extraction. The synthesized materials were systematically characterized. Results demonstrated that methyltrimethoxy modified magnetic mesoporous silica with p-toluenesulfonic acid as the catalyst has a relatively smaller aperture and extreme hydrophobicity (water contact angle of 135°).

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The concentration, potential source and health risks of 16 polycyclic aromatic hydrocarbons (PAHs) in the atmosphere of Dajiuhu, Shennongjia, China, were studied. Polyurethane foam (PUF) Passive air samplers (PAS) were settled. The results indicated that the total concentrations of 16 PAHs in different samples ranged from 6.

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