Complete genome sequence of a new member of the genus Badnavirus infecting nettle (Urtica dioica).

A new badnavirus was discovered in nettle plants (Urtica dioica L., family Urticaceae) with vein banding symptoms using high-throughput sequencing. This virus was provisionally named "nettle badnavirus 1" (NBV 1).

High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions.

We report the high NH uptake in a series of copper-carboxylate materials, namely MFM-100, MFM-101, MFM-102, MFM-126, MFM-127, MFM-190(F), MFM-170, and Cu-MOP-1a. At 273 K and 1 bar, MFM-101 shows an exceptional uptake of 21.9 mmol g.

Phase shaping of dual-pumped Brillouin-Kerr frequency combs.

We investigate the spectral phase characteristics of dual-pumped Kerr frequency combs generated in a bichromatic Brillouin fiber laser architecture with normal dispersion, producing square-like pulse profiles. Using a pulse shaper, we measure the relative phase between the pump Stokes and adjacent lines, revealing a symmetric phase relationship. Our results highlight good phase coherence of the comb.

Analysis of a Cu-Doped Metal-Organic Framework, MFM-520(Zn Cu ), for NO Adsorption.

MFM-520(Zn) confines dimers of NO with a high adsorption of 4.52 mmol g at 1 bar at 298 K. The synthesis and the incommensurate structure of Cu-doped MFM-520(Zn) are reported.

First Report and Complete Genome Characterization of Cherry Virus A and Little Cherry Virus 1 from Russia.

Virus diseases affect the yield and fruit quality and shorten the productive life of stone fruits ( spp. in the family ). Of over fifty known viruses infecting these crops, cherry virus A (CVA) is among the most common, and little cherry virus 1 (LChV1) is one of the most economically important.

[Analysis of the Complete Tomato Aspermy Virus Genomes Suggests Reassortment in Russian Isolates from Chrysanthemum].

Tomato aspermy virus (TAV, genus Cucumovirus from the family Bromoviridae) is one of the most common and harmful chrysanthemum viruses, causing severe flower distortion, size reduction, and color breaking. Metatranscriptome sequencing of chrysanthemum plants of the Ribonette and Golden Standard cultivars from the collection of the Nikita Botanical Garden (Yalta, Republic of Crimea) generated TAV-related RNA reads. The complete genomes of two Russian isolates of the virus were assembled from the reads.

Direct Conversion of Methane to Ethylene and Acetylene over an Iron-Based Metal-Organic Framework.

Conversion of methane (CH) to ethylene (CH) and/or acetylene (CH) enables routes to a wide range of products directly from natural gas. However, high reaction temperatures and pressures are often required to activate and convert CH controllably, and separating C products from unreacted CH can be challenging. Here, we report the direct conversion of CH to CH and CH driven by non-thermal plasma under ambient (25 °C and 1 atm) and flow conditions over a metal-organic framework material, MFM-300(Fe).

Analysis of the dispersive Fourier transform dataset using dynamic mode decomposition: evidence of multiple vibrational modes and their interplay in a three-soliton molecule.

We demonstrate that the dynamic mode decomposition technique can effectively reduce the amount of noise in the dispersive Fourier transform dataset and allow for finer quantitative analysis of the experimental data. We therefore show that the oscillation pattern of a soliton molecule actually results from the interplay of several elementary vibration modes.

Control of evolution of porous copper-based metal-organic materials for electroreduction of CO to multi-carbon products.

Electrochemcial reduction of CO to multi-carbon (C) products is an important but challenging task. Here, we report the control of structural evolution of two porous Cu(ii)-based materials (HKUST-1 and CuMOP, MOP = metal-organic polyhedra) under electrochemical conditions by adsorption of 7,7,8,8-tetracyanoquinodimethane (TNCQ) as an additional electron acceptor. The formation of Cu(i) and Cu(0) species during the structural evolution has been confirmed and analysed by powder X-ray diffraction, and by EPR, Raman, XPS, IR and UV-vis spectroscopies.

Modulation of Uptake and Reactivity of Nitrogen Dioxide in Metal-Organic Framework Materials.

We report the modulation of reactivity of nitrogen dioxide (NO ) in a charged metal-organic framework (MOF) material, MFM-305-CH in which unbound N-centres are methylated and the cationic charge counter-balanced by Cl ions in the pores. Uptake of NO into MFM-305-CH leads to reaction between NO and Cl to give nitrosyl chloride (NOCl) and NO anions. A high dynamic uptake of 6.

A new strategy for improving cytotoxicity of a copper complex toward metastatic melanoma cells unveiled by EPR spectroscopy.

A novel strategy of improving cytotoxicity against metastatic melanoma cells using an oxindolimine copper(ii) complex immobilized and dimerized on a modified Polyhedral Oligomeric Silsesquioxane (POSS) matrix was developed, as revealed by electron paramagnetic resonance (EPR) spectroscopy. An assured correlation between continuous-wave (CW) and pulsed EPR spectroscopies provided a complete characterization of the actual active species, its coordination environment, as well as the efficiency/selectivity of the bioconjugate materials.

Phase space topology of four-wave mixing reconstructed by a neural network.

The dynamics of ideal four-wave mixing in optical fiber is reconstructed by taking advantage of the combination of experimental measurements together with supervised machine learning strategies. The training data consist of power-dependent spectral phase and amplitude recorded at the output of a short fiber segment. The neural network is shown to be able to accurately predict the nonlinear dynamics over tens of kilometers, and to retrieve the main features of the phase space topology including multiple Fermi-Pasta-Ulam recurrence cycles and the system separatrix boundary.

Bimetallic Aluminum- and Niobium-Doped MCM-41 for Efficient Conversion of Biomass-Derived 2-Methyltetrahydrofuran to Pentadienes.

The production of conjugated C4-C5 dienes from biomass can enable the sustainable synthesis of many important polymers and liquid fuels. Here, we report the first example of bimetallic (Nb, Al)-atomically doped mesoporous silica, denoted as AlNb-MCM-41, which affords quantitative conversion of 2-methyltetrahydrofuran (2-MTHF) to pentadienes with a high selectivity of 91 %. The incorporation of Al and Nb sites into the framework of AlNb-MCM-41 has effectively tuned the nature and distribution of Lewis and Brønsted acid sites within the structure.

Characterization of Divergent Grapevine Badnavirus 1 Isolates Found on Different Fig Species ( spp.).

Fig mosaic disease is spread worldwide and is believed to have a viral etiology. Divergent isolates of grapevine badnavirus 1 (GBV1), named fGBV1, were discovered on , , , and in the fig germplasm collection of the Nikita Botanical Gardens, Russia, expanding the list of viruses infecting this crop. The complete genomes of five fGBV1 isolates from and trees were determined using high-throughput and Sanger sequencing.

Evolution of bismuth-based metal-organic frameworks for efficient electroreduction of CO.

Understanding the structural and chemical changes that reactive metal-organic frameworks (MOFs) undergo is crucial for the development of new efficient catalysts for electrochemical reduction of CO. Here, we describe three Bi(iii) materials, MFM-220, MFM-221 and MFM-222, which are constructed from the same ligand (biphenyl-3,3',5,5'-tetracarboxylic acid) but which show distinct porosity with solvent-accessible voids of 49.6%, 33.

Data-driven model discovery of ideal four-wave mixing in nonlinear fibre optics.

We show using numerical simulations that data driven discovery using sparse regression can be used to extract the governing differential equation model of ideal four-wave mixing in a nonlinear Schrödinger equation optical fibre system. Specifically, we consider the evolution of a strong single frequency pump interacting with two frequency detuned sidebands where the dynamics are governed by a reduced Hamiltonian system describing pump-sideband coupling. Based only on generated dynamical data from this system, sparse regression successfully recovers the underlying physical model, fully capturing the dynamical landscape on both sides of the system separatrix.

Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site.

Natural gas, consisting mainly of methane (CH), has a relatively low energy density at ambient conditions (~36 kJ l). Partial oxidation of CH to methanol (CHOH) lifts the energy density to ~17 MJ l and drives the production of numerous chemicals. In nature, this is achieved by methane monooxygenase with di-iron sites, which is extremely challenging to mimic in artificial systems due to the high dissociation energy of the C-H bond in CH (439 kJ mol) and facile over-oxidation of CHOH to CO and CO.

New Cherry-Adapted Plum Pox Virus Phylogroups Discovered in Russia.

Plum pox virus (PPV) is the most pathogenic virus of stone fruit crops worldwide. Unusual PPV isolates were discovered on sour cherry ( L.) and steppe cherry ( Pall.

Highly divergent isolates of chrysanthemum virus B and chrysanthemum virus R infecting chrysanthemum in Russia.

Background: Chrysanthemum is a popular ornamental and medicinal plant that suffers from many viruses and viroids. Among them, chrysanthemum virus B (CVB, genus , family ) is widespread in all chrysanthemum-growing regions. Another carlavirus, chrysanthemum virus R (CVR), has been recently discovered in China.

Plum Pox Virus Strain C Isolates Can Reduce Sour Cherry Productivity.

The impact of plum pox virus (PPV) on sour cherry ( L.) productivity has been studied by comparing the yield of PPV-infected and PPV-free fruit-bearing trees. A total of 152 16- to 17-year-old trees of nine cultivars and hybrids were surveyed in the production orchards (cultivar collection and hybrid testing plots) in the Republic of Tatarstan, Russia.