Crystallization-Induced Emission Enhancement of a Deep-Blue Luminescence Material with Tunable Mechano- and Thermochromism.

Organic luminescent materials with the ability to reversibly switch the luminescence when subjected to external stimuli have attracted considerable interest in recent years. However, the examples of luminescent materials that exhibit multiresponsive properties are rarely reported. In this work, a new stimuli-responsive dye P1 is designed and synthesized with two identical chromophores of naphthalimide, one at each side of an amidoamine-based spacer.

Tetraphenylethene-Induced Free Volumes for the Isomerization of Spiropyran toward Multifunctional Materials in the Solid State.

Solid-state photochromic materials with reversible and adjustable optical properties are very appealing because of their wide prospects in advanced functional materials. Yet, it remains a significant challenge to develop such materials in the solid state. In this study, a tetraphenylethene derivative (SP-TPE-SP)-based solid-state photoswitch, which exhibits reversible photochromism in the solid state, was constructed.