We present experimental observations of K_{β} emission from highly charged Mg ions at solid density, driven by intense x rays from a free electron laser. The presence of K_{β} emission indicates the n=3 atomic shell is relocalized for high charge states, providing an upper constraint on the depression of the ionization potential. We explore the process of state relocalization in dense plasmas from first principles using finite-temperature density functional theory alongside a wave-function localization metric, and find excellent agreement with experimental results.
View Article and Find Full Text PDFPhilos Trans A Math Phys Eng Sci
August 2023
Inner-shell [Formula: see text] X-ray lasers have been created by pumping gaseous, solid, and liquid targets with the intense X-ray output of free-electron lasers (FELs). For gaseous targets lasing relies on the creation of [Formula: see text]-shell core holes on a time-scale short compared with filling via Auger decay. In the case of solid and liquid density systems, collisional effects will also be important, affecting not only populations but also line-widths, both of which impact the degree of overall gain, and its duration.
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