Experimental study and mechanism analysis of high-efficiency adsorption of PCDD/Fs on N-doped hierarchical porous biochar.

Adsorption removal of PCDD/Fs from flue gas is one of the important technologies for reducing environmental PCDD/Fs emissions. However, due to the lack of systematic research on the adsorption mechanism of PCDD/Fs, commercial activated carbon (AC) with a single pore size distribution and lack of surface functional groups has poor adsorption and removal efficiency for PCDD/Fs. Therefore, this study first used corncob as a raw material and prepared N-doped hierarchical porous biochar (NHPB) using a one-step activation method for efficient removal of PCDD/Fs.

Degradation of dioxins in chelated municipal solid waste incineration fly ash by low-temperature pyrolysis.

In this study, low-temperature pyrolysis is applied to raw and chelated municipal solid waste incinerator fly ash to degrade and remove PCDD/F (polychlorinated dibenzo-p-dioxins, and dibenzofurans) and corresponding I-TEQs (international toxic equivalents), respectively. Additionally, PCDD/F degradation pathways are identified based on PCDD/F signatures. From the analysis of the average signal intensity of dioxin isomers in thermally treated fly ashes, the PCDD/F degradation rate was between 89.

Effects of heat treatment on rumen degradability and protein intestinal digestibility of black soldier fly (Hermetia illucens L.) in goat.

The black soldier fly larvae (BSF) are used as a substitute for soybean meal due to their high crude protein content. This experiment aims to assess the impact of heat treatment on the rumen degradability of BSF and protein digestion in the small intestine using the in situ nylon bag method and the three-step in vitro method. This study comprises a total of 8 groups (n = 6).

Effects of black soldier fly larvae (Hermetia illucens L.) as feed supplements on muscle nutrient composition, meat quality, and antioxidant capacity in Qianbei goat.

Objective: Black soldier fly (BSF) as an animal protein feed source is currently becoming a hot research topic. This study investigated the effects of the BSF as a protein feed source for goats on slaughter performance, muscle nutrient composition, amino acids, fatty acids, minerals, and antioxidant levels.

Methods: Thirty Qianbei Ma goats (20.

Effects of Black Soldier Fly ( L., BSF) Larvae Addition on In Vitro Fermentation Parameters of Goat Diets.

The purpose of this experiment was to evaluate the effects of different levels of BSF on rumen in vitro fermentation gas production, methane (CH) production, ammonia nitrogen (NH-N), and volatile fatty acids (VFAs). The experiment comprised four treatments, each with five replicates. The control group contained no BSF (BSF0), and the treatment groups contained 5% (BSF5), 10% (BSF10), and 15% (BSF15) BSF, respectively.

Physicochemical properties, mechanism of action of lycopene and its application in poultry and ruminant production.

Lycopene is a kind of natural carotenoid that could achieve antioxidant, anti-cancer, lipid-lowering and immune-improving effects by up-regulating or down-regulating genes related to antioxidant, anti-cancer, lipid-lowering and immunity. Furthermore, lycopene is natural, pollution-free, and has no toxic side effects. The application of lycopene in animal production has shown that it could improve livestock production performance, slaughter performance, immunity, antioxidant capacity, intestinal health, and meat quality.

Migration and distribution characteristics of typical organic pollutants in condensable particulate matter of coal-fired flue gas and by-products of wet flue gas desulfurization system.

The wet flue gas desulfurization (WFGD) system of coal-fired power plants shows a good removal effect on condensable particulate matter (CPM), reducing the dust removal pressure for the downstream flue gas purification devices. In this work, the removal effect of a WFGD system on CPM and its organic pollutants from a coal-fired power plant was studied. By analyzing the organic components of the by-products emitted from the desulfurization tower, the migration characteristics of organic pollutants in gas, liquid, and solid phases, as well as the impact of desulfurization towers on organic pollutants in CPM, were discussed.

New mechanistic insight into catalytic decomposition of dioxins over MnO-CeO/TiO catalysts: A combined experimental and density functional theory study.

Elucidation of the catalytic decomposition mechanism of dioxins is pivotal in developing highly efficient dioxin degradation catalysts. In order to accurately simulate the whole molecular structure of dioxins, two model compounds, o-dichlorobenzene (o-DCB) and furan, were employed to represent the chlorinated benzene ring and oxygenated central ring within a dioxin molecule, respectively. Experiments and Density Functional Theory (DFT) calculations were combined to investigate the adsorption as well as oxidation of o-DCB and furan over MnO-CeO/TiO catalyst (denoted as MnCe/Ti).

Synthesis of layered double hydroxides from municipal solid waste incineration fly ash for heavy metal adsorption.

The process of urbanization has resulted in a continuous growth of the production of municipal solid waste, consequently leading to the increase of municipal solid waste incineration fly ash (MSWI FA) over time. This has prompted the need for effective disposal and value-added utilization strategies for MSWI FA. In this study, a hydrothermal method was employed to synthesize CaAl layered double hydroxides (LDHs) using MSWI FA as the raw material.

Use of municipal solid waste incineration fly ash as a supplementary cementitious material: CO mineralization coupled with mechanochemical pretreatment.

The use of municipal solid waste incineration fly ash, commonly referred to as "fly ash", as a supplementary cementitious material (SCM), has been explored to mitigate the CO emissions resulting from cement production. Nevertheless, the incorporation of fly ash as an SCM in mortar has been shown to weaken its compressive strength and increase the risk of heavy metal leaching. In light of these challenges, this study aims to comprehensively evaluate the influence of CO pressure, temperature, and residual water/binder ratio on the CO uptake and compressive strength of mortar when combined with fly ash.

Promoting effect of FeOx addition on the mechanochemically prepared vanadium-based catalyst for real PCDD/Fs removal and mechanism insight.

Industrial-use VOx-based catalysts usually have a higher active temperature window (> 250-300°C), which becomes a "bottleneck" for the practical application of PCDD/Fs catalytic degradation technology. In this work, VOx-FeOx/TiO catalyst prepared via mechanochemically method was investigated for the catalytic removal of PCDD/Fs. The removal efficiency of 1,2-DCBz, pure PCDD/Fs gas generated in the lab, PCDD/Fs from actual flue gas, long-term were studied, and the degradation mechanism was explored using FTIR and TOFMS.

PCDD/F adsorption enhancement over nitrogen-doped biochar: A DFT-D study.

Polychlorinated dibenzo-p-dioxin/furans (PCDD/F) have a great threat to the environment and human health, resulting in controlling PCDD/F emissions to regulation far important for emission source. Considering 2,3,4,7,8-pentachlorodibenzo-p-furan (PeCDF) identified as the most contributor to international toxic equivalent, 2,3,4,7,8-PeCDF can be considered as the target molecule for the adsorption of PCDD/F emission from industries. With the aim to in-depth elucidate how different types of nitrogen (N) species enhance 2,3,4,7,8-PeCDF on the biochar and guide the specific carbon materials design for industries, systematic computational investigations by density functional theory calculations were conducted.

Theoretical and experimental investigation on rapid and efficient adsorption characteristics of microplastics by magnetic sponge carbon.

Microplastic pollution control has always been a thorny problem all over the world. Magnetic porous carbon materials have shown a good development prospect in microplastic adsorption due to their excellent adsorption performance and easy magnetic separation from water. However, the adsorption capacity and rate of magnetic porous carbon on microplastics are still not high, and the adsorption mechanism is not fully revealed, which hinders its further development.

The effect of air pollution control devices in coal-fired power plants on the removal of condensable and filterable particulate matter.

Total particulate matter (TPM), including condensable and filterable particulate matter (CPM and FPM), is one of the pollutants that need to be controlled in the coal combustion process. In this study, CPM and FPM were sampled from sixteen coal-fired power units and two coal-fired industrial units. The removal effects of air pollution control devices equipped in the units on the migration and emission of particles were investigated by analyzing samples from inlets and outlets of apparatus.

Designing low-carbon cement-free binders for stabilization/solidification of MSWI fly ash.

Low-carbon and high-efficiency binder is desirable for sustainable treatment of municipal solid waste incineration fly ash (MSWI FA). In this study, CaO or MgO was used to activate ground granulated blast furnace slag (GGBS) to form calcium silicate hydrate and magnesium silica hydrate gel for stabilization/solidification of hazardous MSWI FA. Experimental results showed that potential toxic elements (PTEs), such as Pb and Zn, significantly inhibited the formation of reaction products in CaO-GGBS system due to the complexation between Ca(OH) and PTEs, whereas PTEs only had insignificant inhibition on transformation from MgO to Mg(OH) in MgO-GGBS system, resulting in lower leachabilities of PTEs and higher mechanical strengths.

Sustainable Valorization of Tomato Pomace () in Animal Nutrition: A Review.

Under the background of the current shortage of feed resources, especially the shortage of protein feed, attempts to develop and utilize new feed resources are constantly being made. If the tomato pomace (TP) produced by industrial processing is used improperly, it will not only pollute the environment, but also cause feed resources to be wasted. This review summarizes the nutritional content of TP and its use and impact in animals as an animal feed supplement.

Adsorption of multicomponent VOCs on various biomass-derived hierarchical porous carbon: A study on adsorption mechanism and competitive effect.

Biomass-derived porous carbon materials are potential adsorbents for VOCs. In this work, biomass-derived nitrogen-doped hierarchical porous carbons (NHPCs) were synthesized by a one-step pyrolysis activation combined with nitrogen doping method from several biomass wastes (corn straw, wheat stalk, bamboo, pine, and corncob). NHPCs have a hierarchical porous structure with micro-meso-macropores distribution, nitrogen doping, large specific surface area, and pore volume.

Inhibition of PCDD/Fs in a full-scale hazardous waste incinerator by the quench tower coupled with inhibitors injection.

The control of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from the flue gas in hazardous waste incinerators (HWIs) is an intractable problem. To figure out the formation mechanism of PCDD/Fs and reduce the emission, a field study was carried out in a full-scale HWI. Ca(OH) & (NH)HPO or CHNS & (NH)HPO were injected into the quench tower, and the detailed inhibition effect on PCDD/Fs formation by the inhibitors coupled with quench tower was studied.

Nutritional Composition of Black Soldier Fly Larvae ( L.) and Its Potential Uses as Alternative Protein Sources in Animal Diets: A Review.

The rapidly growing population has increased demand for protein quantities and, following a shortage of plant-based feed protein sources and the prohibition of animal-based feed protein, has forced the search for new sources of protein. Therefore, humans have turned their attention to edible insects. Black soldier fly larvae (BSFL) ( L.

Influence of different kinds of incinerators on PCDD/Fs: a case study of emission and formation pathway.

Few studies focused on the emission of polychlorinated-ρ-dibenzodioxins and dibenzofurans (PCDD/F) from different kinds of waste incinerators. This study was conducted in a full-scale MSW incineration plant to investigate the influence of different incinerator types on PCDD/F. Experimental results indicated that the 2,3,7,8-PCDD/F concentration in the inlet gas of the air pollution control system (APCS) in the studied fluidized bed was higher (2.

Green photoreduction synthesis of dispersible gold nanoparticles and their direct in situ assembling in multidimensional substrates for SERS detection.

Gold nanoparticles (AuNPs) and their composites have been applied in surface-enhanced Raman scattering (SERS) detection methods, owing to their stable and excellent surface plasmon resonance. Unfortunately, methods for synthesizing AuNPs often require harsh conditions and complicated external steps. Additionally, removing residual surfactants or unreacted reductants is critical for improving the sensitivity of SERS detection, especially when employing AuNPs-assembled multidimensional substrates.

Assessment of recycling methods and processes for lithium-ion batteries.

This review discusses physical, chemical, and direct lithium-ion battery recycling methods to have an outlook on future recovery routes. Physical and chemical processes are employed to treat cathode active materials which are the greatest cost contributor in the production of lithium batteries. Direct recycling processes maintain the original chemical structure and process value of battery materials by recovering and reusing them directly.

PCDD/Fs from a large-scale municipal solid waste incinerator under transient operations: Insight formation pathways and optimal reduction strategies.

Polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) emissions from the transient operation of municipal solid waste incinerators can reach up to 690 ng/Nm, as measured in this study. To control the extreme emissions to meet the national standard, the formation pathways of PCDD/F were investigated under transient operations (cold start-up, hot start-up, and after start-up) and normal operations. Compared with normal operations, transient operations facilitate the formation of low-chlorinated congeners rather than highly chlorinated congeners.